Effective and Reversible Carbon Dioxide Insertion into Cerium Pyrazolates

摘要

Abstract > The homoleptic pyrazolate complexes [Ce III <sub>4</sub> (Me <sub>2</sub> pz) <sub>12</sub> ] and [Ce IV (Me <sub>2</sub> pz) <sub>4</sub> ] <sub>2</sub> quantitatively insert CO <sub>2</sub> to give [Ce III <sub>4</sub> (Me <sub>2</sub> pz?CO <sub>2</sub> ) <sub>12</sub> ] and [Ce IV (Me <sub>2</sub> pz?CO <sub>2</sub> ) <sub>4</sub> ], respectively (Me <sub>2</sub> pz=3,5‐dimethylpyrazolato). This process is reversible for both complexes, as observed by in?situ IR and NMR spectroscopy in solution and by TGA in the solid state. By adjusting the molar ratio, one molecule of CO <sub>2</sub> per [Ce IV (Me <sub>2</sub> pz) <sub>4</sub> ] complex could be inserted to give trimetallic [Ce <sub>3</sub> (Me <sub>2</sub> pz) <sub>9</sub> (Me <sub>2</sub> pz?CO <sub>2</sub> ) <sub>3</sub> (thf)]. Both the cerous and ceric insertion products catalyze the formation of cyclic carbonates from epoxides and CO <sub>2</sub> under mild conditions. In the absence of epoxide, the ceric catalyst is prone to reduction by the co‐catalyst tetra‐ n ‐butylammonium bromide (TBAB). </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 经络吡唑酸酯复合物[CE iii </ sup> <sub> 4 </ sub> （我 <sub> 2 </ sub> PZ） <sub> 12 </ sub> [CE iv </ sup> （我 <sub> 2 </ sub> PZ） <sub> 4 </ sub> ] <sub> 2 </ sub> 定量插入CO. <sub> 2 </ sub> 给予[ce iii </ sup> <sub> 4 </ sub> （我 <sub> 2 </ sub> PZ？CO. <sub> 2 </ sub> 的） <sub> 12 </ sub> [CE iv </ sup> （我 <sub> 2 </ sub> PZ？CO. <sub> 2 </ sub> 的） <sub> 4 </ sub> 分别（我 <sub> 2 </ sub> Pz = 3,5-二甲基吡唑唑醇。该方法对两个复合物可逆，如溶液中的─IR和NMR光谱在溶液中和固态中的TGA中观察到的。通过调节摩尔比，一个分子CO <sub> 2 </ sub> per [ce. iv </ sup> （我 <sub> 2 </ sub> PZ） <sub> 4 </ sub> 可以插入复合物以给予Trimetallic [CE <sub> 3 </ sub> （我 <sub> 2 </ sub> PZ） <sub> 9 </ sub> （我 <sub> 2 </ sub> PZ？CO. <sub> 2 </ sub> 的） <sub> 3 </ sub> （THF）]。菌株和凝粒插入产品均催化来自环氧化物和CO的环状碳酸盐的形成 <sub> 2 </ sub> 在温和的条件下。在没有环氧化物的情况下，官官催化剂易于通过助催化剂来减少 n </ i> - 溴化铵（TBAB）。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon dioxide&option=203" rel="nofollow">carbon dioxide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cerium&option=203" rel="nofollow">cerium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cycloaddition&option=203" rel="nofollow">cycloaddition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=epoxides&option=203" rel="nofollow">epoxides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pyrazolates&option=203" rel="nofollow">pyrazolates;</a> </p> <div class="translation"> 机译：二氧化碳;铈;环加成;环氧化物;吡唑酸盐; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161796.html">Effective and Reversible Carbon Dioxide Insertion into Cerium Pyrazolates</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第14期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：有效且可逆二氧化碳插入吡唑酯中</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070404515507.html">THE REVERSIBLE INSERTION REACTION OF CARBON DIOXIDE WITH THE W(CO)(5)OH- ANION - 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