Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

Chen Xinglong; Jo Hongil; Ok Kang Min

摘要

Abstract > To design high‐performance mid‐infrared (mid‐IR) nonlinear optical (NLO) materials, we have focused on the combination of a heavy metal lone pair cation, Pb 2+ and mixed oxyhalides. A systematic investigation in PbO‐PbCl <sub>2</sub> ‐PbBr <sub>2</sub> system led us to discover the first examples of NLO lead mixed oxyhalides, namely, Pb <sub>13</sub> O <sub>6</sub> Cl <sub>4</sub> Br <sub>10</sub> , Pb <sub>13</sub> O <sub>6</sub> Cl <sub>7</sub> Br <sub>7</sub> , and Pb <sub>13</sub> O <sub>6</sub> Cl <sub>9</sub> Br <sub>5</sub> . All the reported materials have remarkably comprehensive properties including broad IR transparency (up to 14.0?μm), qualified second harmonic generation (SHG) responses (0.6–0.9×AgGaS <sub>2</sub> ), wide band gaps (3.05–3.21?eV), and ease of crystal growth. Interestingly, a centimeter‐sized single crystal (2.9×1.3×0.5?cm 3 ) of Pb <sub>13</sub> O <sub>6</sub> Cl <sub>9</sub> Br <sub>5</sub> revealing a wide transparent range (0.384–14.0?μm) and high laser damage threshold (LDT) (14.6×AgGaS <sub>2</sub> ) has been successfully grown in an open system. The study suggests that all the reported mixed oxyhalides are outstanding candidates for mid‐IR NLO materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 为了设计高性能中红外线（中红外）非线性光学（NLO）材料，我们专注于重金属孤牌阳离子，PB的组合 2 + </ sup> 和混合氧合。 PBO-PBCL的系统调查 <sub> 2 </ sub> -pbbr. <sub> 2 </ sub> 系统导致我们发现NLO铅混合氧化物的第一个例子，即Pb <sub> 13 </ sub> O. <sub> 6 </ sub> CL. <sub> 4 </ sub> 布鲁斯 <sub> 10 </ sub> ，PB. <sub> 13 </ sub> O. <sub> 6 </ sub> CL. <sub> 7 </ sub> 布鲁斯 <sub> 7 </ sub> ，和pb. <sub> 13 </ sub> O. <sub> 6 </ sub> CL. <sub> 9 </ sub> 布鲁斯 <sub> 5 </ sub> 。所有报告的材料都具有显着的综合性质，包括广泛的红外透明度（最多14.0？μm），合格的二次谐波生成（SHG）响应（0.6-0.9×Aggas <sub> 2 </ sub> ），宽带间隙（3.05-3.21？EV），易于晶体生长。有趣的是，厘米大小的单晶（2.9×1.3×0.5？cm 3 </ sup> ）PB. <sub> 13 </ sub> O. <sub> 6 </ sub> CL. <sub> 9 </ sub> 布鲁斯 <sub> 5 </ sub> 透露宽透明范围（0.384-14.0？μm）和高激光损伤阈值（LDT）（14.6×Aggas <sub> 2 </ sub> ）已成功在开放系统中成功种植。该研究表明，所有报告的混合氧化物都是中红外NLO材料的杰出候选者。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第19期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Xinglong&option=202" target="_blank" rel="nofollow">Chen Xinglong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jo Hongil&option=202" target="_blank" rel="nofollow">Jo Hongil;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ok Kang Min&option=202" target="_blank" rel="nofollow">Ok Kang Min;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistrySogang University35 Baekbeom-ro Mapo-gu Seoul 04107 Korea;</p> <p>Department of ChemistrySogang University35 Baekbeom-ro Mapo-gu Seoul 04107 Korea;</p> <p>Department of ChemistrySogang University35 Baekbeom-ro Mapo-gu Seoul 04107 Korea;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=crystal growth&option=203" rel="nofollow">crystal growth;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal mixed oxyhalides&option=203" rel="nofollow">metal mixed oxyhalides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mid-IR NLO materials&option=203" rel="nofollow">mid-IR NLO materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nonlinear optics&option=203" rel="nofollow">nonlinear optics;</a> </p> <div class="translation"> 机译：晶体生长;金属混合氧化物;中红外NLO材料;非线性光学; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028161751.html">Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Xinglong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Xinglong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jo Hongil&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jo Hongil,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ok Kang Min&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ok Kang Min </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铅混合氧化物满足高性能中红外非线性光学材料的所有基本要求</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162357.html">Inside Cover: Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials (Angew. Chem. Int. Ed. 19/2020)</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Xinglong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Xinglong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jo Hongil&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jo Hongil,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ok Kang Min&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ok Kang Min </a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：内盖：铅混合氧化物满足高性能中红外非线性光学材料的所有基本要求（Angew.Chem.Int.SED。19/2020）</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_coordination-chemistry-reviews_thesis/0204119681093.html">Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Weikang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Weikang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mei Dajiang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mei Dajiang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liang Fei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liang Fei,</a> <a href="/journal-foreign-667/" target="_blank" rel="nofollow" class="tuijian_authcolor">Coordination chemistry reviews .</a> <span>2020</span><span>,第Octa期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于四面体中红外非线性光学材料的四面体布置模式与光学性能之间的固有规律</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-250055_thesis/0705010126608.html">Superior performances from fabricated microstructures on MBE-grown IV-VI lead salt materials for mid-infrared applications</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shaibal Mukherjee&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shaibal Mukherjee,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=S. Jain&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">S. Jain,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=J. P. Kar&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">J. P. Kar,</a> <a href="/conference-foreign-250055/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Workshop on the Physics of Semiconductor Devices .</a> <span>2007</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于中红外应用的MBE-种植IV-VI铅盐材料的制造微观结构的优异性能</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061572314.html">Crystal growth and near infrared optical properties of Pr 3+ doped lead halide materials for resonantly pumped eye safe laser applications.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jones, Ivy Krystal.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jones, Ivy Krystal. </a> <span>2015</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Pr 3+掺杂的卤化铅材料的晶体生长和近红外光学性质，用于共振泵浦对眼睛安全的激光应用。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040002782541.html">New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shu-Fang Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shu-Fang Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xiao-Ming Jiang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xiao-Ming Jiang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu-Hang Fan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yu-Hang Fan,</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：设计有前途的中红外非线性光学材料的新策略：缩小带隙以实现较大的非线性光学效率并降低高激光诱导损伤阈值的热效应</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000131784753.html">Innentitelbild: Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials (Angew. Chem. 19/2020)</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xinglong Chen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xinglong Chen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hongil Jo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hongil Jo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kang Min Ok&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kang Min Ok </a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Innentitelbild：铅混合氧化物满足高性能中红外非线性光学材料（Angew.Chem.19/2020）的所有基本要求</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_ad_thesis/02071853391.html">DEPSCOR-95: Development of Nonlinear Optical Materials for Optical Parametric Oscillator and Frequency Conversion Applications in the Near- and Mid-Infrared</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Halliburton, L. E. &option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Halliburton, L. E. ,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Giles, N. C. &option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Giles, N. C. ,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Myers, T. H.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Myers, T. H. </a> <span>1999</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：DEpsCOR-95：用于光学参量振荡器和近红外和中红外频率转换应用的非线性光学材料的开发</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201295488877.html">四配位硫属中红外非线性光学材料结构-性能分析</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=候凤娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 候凤娟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=梅大江&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,梅大江</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=汪伟康&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,汪伟康</a> <span> <a href="/journal-cn-56955/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 人工晶体学报 </a> </span> <span> . 2020</span><span>,第8期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_infrared_thesis/0201294229017.html">理化所发表中红外金属卤化物非线性光学材料研究综述</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . </a> <span> <a href="/journal-cn-8746/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 红外 </a> </span> <span> . 2018</span><span>,第11期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-inorganic-chemistry_thesis/0201250698885.html">KBi4F13:一个具有高激光损伤阈值的中红外非线性光学材料</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴奇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 吴奇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘宏鸣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘宏鸣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜方超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姜方超</a> <span> <a href="/journal-cn-15070/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 无机化学学报 </a> </span> <span> . 2015</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-tianjin-college-commerce_thesis/0201265707745.html">类混合所有制靠近混合所有制路径研究——我国商业银行推行混合所有制的解决途径</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陆岷峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陆岷峰</a> <span> <a href="/journal-cn-39021/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 天津商务职业学院学报 </a> </span> <span> . 2014</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-tianjin-finance-trade-management-cadre-college_thesis/0201258212540.html">类混合所有制靠近混合所有制路径研究——我国商业银行推行混合所有制的解决途径</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陆岷峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陆岷峰</a> <span> <a href="/journal-cn-2390/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 天津市财贸管理干部学院学报 </a> </span> <span> . 2014</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-61626_thesis/020222752048.html">国企改革背景下的混合所有制企业竞争力研究——以国有控股的制造业混合所有制企业为例</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胡锋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胡锋</a> <span> <a href="/conference-cn-61626/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . “一带一路”与中国企业管理国际化学术研讨会暨中国企业管理研究会2017年年会 </a> <span> <span> . 2017</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316004232.html">混合所有制改革对企业创新能力提升的影响研究——以中国联通混合所有制改革为例</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙家伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孙家伟</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204944926.html">一种硝酸铅的应用，中红外氟氧化物硅酸盐稀土掺杂玻璃及其制备</a> <b>[P]</b> . <span> 中国专利： CN109626817B </span> <span> . 2022.03.04</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120100515947.html">一种硝酸铅的应用，中红外氟氧化物硅酸盐稀土掺杂玻璃及其制备</a> <b>[P]</b> . <span> 中国专利： CN109626817A </span> <span> . 2019-04-16</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130429279826.html">Method for regulating light output of frequency-converted laser beam received by nonlinear optical arrangement, involves adjusting fundamental laser beam with fundamental wavelength by nonlinear optical arrangement</a> <b>[P]</b> . <span> 外国专利：  DE102007032253A1 </span> <span> . 2009-01-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：调节非线性光学装置接收的变频激光束的光输出的方法，包括通过非线性光学装置调节基本波长的基本激光束 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130400514899.html">POLYFLUOROAROMATIC POLYIMIDE MATRICES FOR NONLINEAR OPTICAL POLYMER MATERIALS, NONLINEAR OPTICAL POLYMER MATERIALS AND METHODS FOR PRODUCTION THEREOF</a> <b>[P]</b> . <span> 外国专利：  RU2713164C1 </span> <span> . 2020-02-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于非线性光学聚合物材料的多氟代聚酰亚胺基体，非线性光学聚合物材料及其生产方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130450063825.html">Optical coupler using nonlinear optics for near-field microscope probe tip, spectroscopic measuring device, etc., has end of waveguide extending to infrared or microwave emission region of nonlinear optical material</a> <b>[P]</b> . <span> 外国专利：  DE19841736A1 </span> <span> . 2000-04-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：近场显微镜探针，光谱测量装置等使用非线性光学器件的光耦合器，其波导末端延伸至非线性光学材料的红外或微波发射区域 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028161751','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704028161751down" data-source="7," data-out-id="Q7c2cjSyJa64LvRVqNYAya4i5wHWqzKW/hEEKbZAelCmWgZSh+EI5k+HVd5HHe8H," data-f-source-id="7" data-title="Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="19011" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>