Chemical Sample Processing for Combined Selenium Isotope and Selenium‐Tellurium Elemental Investigation of the Earth's Igneous Reservoirs

Yierpan Aierken; K?nig Stephan; Labidi Jabrane; Kurzawa Timon; Babechuk Michael G.; Schoenberg Ronny

摘要

Abstract > The redox‐sensitive, chalcophile, and volatile Se stable isotope system offers new perspectives to investigate the origin and evolution of terrestrial volatiles and the roles of magmatic and recycling processes in the development of the redox contrast between Earth's reservoirs. Selenium isotope systematics become more robust in a well‐constrained petrogenetic context as can be inferred from Se‐Te elemental signatures of sulfides and igneous rocks. In this study, we present a high‐yield chemical sample processing method that allows the determination of Se‐Te concentrations and Se isotope composition from the same sample digest of silicate rocks by hydride generation isotope dilution (ID) quadrupole inductively coupled plasma mass spectrometry (ICP‐MS) and double spike (DS) multicollector (MC)‐ICP‐MS, respectively. Our procedure yields ～80% Se‐Te recoveries with quantitative separation of relevant interfering elements such as Ge and HG‐buffering metals. Replicate analyses of selected international reference materials yield uncertainties better than 0.11‰ (2 s.d.) on δ 82/76 Se and 3% (r.s.d.) on Se concentration for DS MC‐ICP‐MS determinations for as low as ～10 ng sample Se. The precision of Se‐Te concentration measurements by ID ICP‐MS is better than 3% and 5% (r.s.d.) for total amounts of ～0.5–1 ng Se and ～0.2–0.5 ng Te, respectively. The basaltic reference materials have variable Se‐Te contents, but their δ 82/76 Se values are rather uniform (on average 0.23?±?0.14‰; 2 s.d.) and different from the chondritic value. This altogether provides the methodology and potential to extend the limited data set of coupled Se isotope and Se‐Te elemental systematics of samples relevant to study the terrestrial igneous inventory. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”> <标题类型=“main”>抽象</ title> > 氧化还原敏感，金发乳酸和挥发性SE稳定同位素系统提供了新的视角，以研究陆地挥发物的起源和演变以及魔法和回收过程在地球储层之间氧化还原对比的发展中的作用。硒同位素系统在受到良好约束的血散性上下文中变得更加稳健，可以从硫化物和火岩的SE-TE元素签名中推断出来。在这项研究中，我们提出了一种高产化学样品加工方法，允许通过氢化物产生同位素稀释（ID）四极电感耦合等离子体质谱法（ ICP-MS）和双尖峰（DS）多电阻器（MC）-ICP-MS分别。我们的程序产生〜80％的SE-TE回收率，其定量分离相关干扰元素，如GE和HG缓冲金属。所选国际参考资料的复制分析产生优于0.11‰（2 s.D.）的不确定性 82/76 </ sup> SE和3％（R.S.D.）对DS MC-ICP-MS测定的SE浓度低至约10ng样品SE。 ID ICP-MS的SE-TE浓度测量的精度优于3％和5％（R.S.D.），分别为0.5-1ng SE和〜0.2-0.5ng TE。玄武岩参考材料具有可变的SE-TE含量，但它们的δ 82/76 </ sup> SE值相当均匀（平均0.23？±0.14‰; 2 s.D.）和不同于白胸项值。这完全提供了延长有限的SE同位素和SE-TE元素系统的有限数据集的方法和潜力，与研究陆地火导库存相关。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-23285/'>《Geochemistry, geophysics, geosystems》</a> <b style="margin: 0 2px;">|</b><span>2018年第2期</span><b style="margin: 0 2px;">|</b><span>共18页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yierpan Aierken&option=202" target="_blank" rel="nofollow">Yierpan Aierken;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=K?nig Stephan&option=202" target="_blank" rel="nofollow">K?nig Stephan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Labidi Jabrane&option=202" target="_blank" rel="nofollow">Labidi Jabrane;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kurzawa Timon&option=202" target="_blank" rel="nofollow">Kurzawa Timon;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Babechuk Michael G.&option=202" target="_blank" rel="nofollow">Babechuk Michael G.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schoenberg Ronny&option=202" target="_blank" rel="nofollow">Schoenberg Ronny;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Isotope Geochemistry Department of GeosciencesUniversity of TübingenTübingen Germany;</p> <p>Isotope Geochemistry Department of GeosciencesUniversity of TübingenTübingen Germany;</p> <p>Isotope Geochemistry Department of GeosciencesUniversity of TübingenTübingen Germany;</p> <p>Isotope Geochemistry Department of GeosciencesUniversity of TübingenTübingen Germany;</p> <p>Department of Earth SciencesMemorial University of NewfoundlandSt. John's Newfoundland and Labrador Canada;</p> <p>Isotope Geochemistry Department of GeosciencesUniversity of TübingenTübingen Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/163.html" title="地球物理学">地球物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=selenium isotope&option=203" rel="nofollow">selenium isotope;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tellurium&option=203" rel="nofollow">tellurium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=double spike&option=203" rel="nofollow">double spike;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=MC‐ICP‐MS&option=203" rel="nofollow">MC‐ICP‐MS;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silicate rocks&option=203" rel="nofollow">silicate rocks;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chromatography&option=203" rel="nofollow">chromatography;</a> </p> <div class="translation"> 机译：硒同位素;碲;双穗;MC-ICP-MS;硅酸盐岩石;色谱法; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023360806.html">Chemical Sample Processing for Combined Selenium Isotope and Selenium‐Tellurium Elemental Investigation of the Earth's Igneous Reservoirs</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yierpan Aierken&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yierpan Aierken,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=K?nig Stephan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">K?nig Stephan,</a> <a 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑松&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郑松</a> <span> <a href="/journal-cn-4949/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 贵州地质 </a> </span> <span> . 2015</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_rock-mineral-analysis_thesis/0201216595209.html">多目标生态地球化学调查土壤样品中砷硒锑有效态分析方法的商榷</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=汤志云&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 汤志云</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖灵&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,肖灵</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张培新&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张培新</a> <span> <a href="/journal-cn-7819/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 岩矿测试 </a> </span> <span> . 2004</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-37511_thesis/020221595658.html">用钼酸铵催化消解-氢化物发生原子吸收光谱法测定环境样品中的痕量元素硒（Se）</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王一武&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王一武</a> <span> <a href="/conference-cn-37511/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国环境科学学会环境与分析监测专业委员会年会 </a> <span> <span> . 1987</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316295896.html">基于单元素碲和三元素硒氧化铋纳米材料的制备及其光电性质研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韩理想&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 韩理想</a> <span> . 2021</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204258818.html">从废杂阳极铜泥中浸出硒和碲的方法以及提取硒和碲的方法</a> <b>[P]</b> . <span> 中国专利： CN110615413B </span> <span> . 2021.02.26</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061203797268.html">一种用于热电材料的锑碲硒基体合金的构建方法、锑碲硒基热电材料</a> <b>[P]</b> . <span> 中国专利： CN109671840B </span> <span> . 2020.06.19</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130448222874.html">Chemical maturing of a silver halide emulsion containing a crown ether involves using at least one selenium or tellurium compound without selenium or tellurium hydride bonds</a> <b>[P]</b> . <span> 外国专利：  DE19924669A1 </span> <span> . 2000-11-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含有冠醚的卤化银乳剂的化学成熟涉及使用至少一种不具有硒或碲化氢键的硒或碲化合物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130454979929.html">Manner and the constituent in order to make the growth of the tumor decrease takusan chemical compound and the tellurium and/or with the combined use of selenium compound</a> <b>[P]</b> . <span> 外国专利：  JPH10510812A </span> <span> . 1998-10-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：为了使肿瘤的生长减少takusan化合物和碲和/或与硒化合物组合使用的方式和成分 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130405166167.html">METHOD FOR SEPARATING SELENIUM AND TELLURIUM FROM MIXTURE CONTAINING SELENIUM AND TELLURIUM</a> <b>[P]</b> . <span> 外国专利：  JP2019189891A </span> <span> . 2019-10-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: 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