Ligand directed structural diversity and magnetism in copper(II)-azido assemblies with isomeric aminopyridines: synthesis, structure, magnetism and theoretical studies

摘要

Four new copper complexes, viz. [{Cu(2-aminopyridine)(N-3)(2)(H2O)}(2)](n) (1), [Cu-3(3-aminopyridine)(2)(N-3)(6)](n) (2), [{Cu(3-aminopyridine)(N-3)(2)}(2)](n) (3), and [Cu(4-aminopyridine)(2)(N-3)(2)](n) (4), have been synthesized with isomeric aminopyridines, viz. 2-aminopyridine (2-ap), 3-aminopyridine (3-ap), and 4-aminopyridine (4-ap), to probe the role of ligand and reactant molar ratios in directing the polynuclear assemblage and the associated magnetic properties. Ligand geometry is quite influential as can be seen through the versatile structures formed, viz. a hydrogen bonded layer of mu-1,1 azide bridged Cu dimers in 1; a network of two different types of dimers (Cu1-Cu2 & Cu3-Cu3') involving mu-1,1; mu-1,3; mu-1,1,3; & mu-1,1,3,3 azide bridges in 2; a ladder structure in which mu-1,1 azide bridges form the rungs and mu-1,3 azide bridges form the rails of the ladder in 3; and a 1-D polymer chain involving mu-1,1 azide bridges in 4. Consistent with the bridge geometry, compounds 1 & 2 display ferromagnetic interactions, while 3 & 4 display antiferromagnetic interactions. The rather unexpected antiferromagnetic interactions in 3, in spite of mu-1,1 azide bridged rungs may be due to the crossover near the bridge angle. The ferromagnetic interactions in 1 and 2 are supported by DFT calculations.