Influences of Dicumyl Peroxide on Morphology and Mechanical Properties of Polypropylene/Poly(styrene-b-butadiene-b-styrene) Blends via Vane-Extruder

摘要

Polypropylene (PP) and poly(styrene-b-butadiene-b-styrene) block copolymer (SBS) were melt-blended in the presence of initiator system. Dicumyl peroxide (DCP)/Triallyl isocyanurate (TAIC) via self-deigned VE, aiming at in situ reactive compatibilization of toughed PP/SBS blend. The reactivity, morphology and mechanical properties of PP/SBS/DCP/TAIC blends were studied. Online torque detection was conducted to monitor changes in viscosities of reactive compatibilized blends, which could give proof of the interfacial grafted reaction induced by DCP/TAIC system. The effect of reactive compatibilization on the dispersed particles sizes and interfacial adhesion was studied by scanning electron microscopy. Analysis on mechanical performance revealed the impact strength improved after treated by initiator system, moreover, the impact-fractured surface observation showed, the failure mode changed from debonding mechanism of neat 50PP/50SBS blend to plastic deformation mechanism of blend containing 3.0 phr initiator system. With improved interfacial adhesion, compatibilized blends not only were toughened but also exhibited enhanced tensile strength and thermal stability. Dynamic mechanical analysis showed a reduction of Tg between PP phase and the PB segments in SBS phase, indicating reactive compatibilization of the blend was achieved. In the final part, a brief discussion was given about the dominant effects from chain scission of PP matrix to intergrafting reactions of PP and SBS, under different content of DCP/TAIC initiator system. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41543.