Miniemulsion and conventional emulsion copolymerization of styrene and butadiene: Effect of process on gel content

摘要

The properties of Styrene/butadiene copolymers obtained by conventional emulsion and miniemulsion polymerizations were studied. Thin layer chromatography with flame ionization detection was used to determine the gel fraction of the copolymer in the latex particles as a function of conversion. It was found that the gel formation began at a higher conversion in the miniemulsion polymerization when compared with that in the conventional process. Also, a lower glass transition temperature was noted at the lowest conversion sampled (similar to 25%), implying a higher initial butadiene monomer concentration within the nucleated miniemulsion monomer droplets when compared with particles formed conventionally. (c) 2006 Wiley Periodicals, Inc.