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首页> 外文期刊>International Journal of Quantum Chemistry >Energies, fine structures, and radiative lifetimes for the multiexcited quartet states of B-like oxygen
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Energies, fine structures, and radiative lifetimes for the multiexcited quartet states of B-like oxygen

机译:B型氧多激发四重态的能量,精细结构和辐射寿命

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摘要

Energies for the multiexcited states 1s ~22s~2pnl and 1s ~22p ~2nl ~4P ~(e,o) (n ≥ 2) of B-like oxygen are calculated using Rayleigh-Ritz variation method with configuration interaction. The mass polarization and relativistic corrections are obtained with first-order perturbation theory. Configuration structures of the high-lying multiexcited series are identified by energies and contribution to normalization of angular-spin components. These structures are further checked by calculations of relativistic corrections and fine structure splittings. Hyperfine parameters and hyperfine coupling constants are calculated for the first time. Wavelengths including quantum electrodynamic effect and higher-order relativistic corrections and lifetimes are also calculated. These results are compared with available results in the literature.
机译:利用具有构型相互作用的瑞利-里兹变异法,计算了Bs型氧的多激发态1s〜22s〜2pnl和1s〜22p〜2nl〜4P〜(e,o)(n≥2)的能量。利用一阶扰动理论获得了质量极化和相对论校正。高层多激发序列的构型结构通过能量和对自旋角分量归一化的贡献来识别。通过相对论校正和精细结构分裂的计算进一步检查了这些结构。首次计算超精细参数和超精细耦合常数。还计算了包括量子电动力学效应和高阶相对论校正和寿命的波长。将这些结果与文献中的可用结果进行比较。

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