A Single-Chain Magnet Tape Based on Hexacyanomanganate(III)

摘要

The tape-like chain {[(tptz)Mn-II(H2O)-Mn-III(CN)(6)](2)Mn-II(H2O)(2)}(n)center dot 4nMeOH center dot 2nH(2)O based on the anisotropic building block hexacyanomanganate(III) exhibits long-range magnetic ordering below 5.1 K as well as single-chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7) K.