Addition of Dimethylaminobismuth to Aldehydes, Ketones, Alkenes, and Alkynes

摘要

Bismuth is a rare case of a nearly nontoxic heavy element that is used in medical applications.Nitrogen-containing compounds play an important role in many biologically active systems as well as in organic building blocks, new materials. and fine chemicals.Bismuth amido complexes are well established in main-group chemistry and we studied the beneficial influence of chelating N-ligands on the reactivity of bismuth some years ago.