Unexpected Reactions of [Ag(NCCH3)3][(V2O3)2(RPO3)4 is contained in F] Cage Compounds with H2 and NO

摘要

We report herein a strategy for the preparation of a new type of inorganic-organic hybrid materials that offer unique possibilities for tuning their properties and exhibit unexpected redox behavior with respect to NO and H2.The strategy involves the use of a fluoride-templated vanadium cage [(V2O3)2(RPO3)4 is contained to F]~-as a building block linked by coordinated transition-metal fragments to give [M~(n+)L_x][(V2O3)2-(RPO3)4 is contained to F]_n(M = metal ion,L = ligand,R = organic group).