Wear performance of alumina-reinforced copper-matrix composites prepared by powder metallurgy

摘要

Copper-alumina composite materials with improved electrical conductivity and tribological properties were developed. The copper-alumina composite materials were prepared by powder metallurgy using nano-Cu/Al_2O_3 powder. The powders were deoxidized from CuO/Al_2O_3 powder synthesized by coprecipitation using NH_4HCO_3 as precipitator and CuSO_4 + NH_4Al(SO_4)_2 as maternal solution. The wear test against 440C stainless steel was performed at room temperature using a ball-on-flat configuration with 300 μm amplitude at various normal loads ranging from 0.1 N to 1 N. The effects of load and mass fraction of Al_2O_3 on the friction coefficient and wear loss were investigated. Results showed that the wear loss first decreased and then increased with an increase in the mass proportion of Al_2O_3 from 1% to 5%. Minimum wear loss was found at 2% proportion, in which the electrical conductivity was 82% of the International Annealed Copper Standard. The friction coefficient of the copper increased slightly with an increase in load. By contrast, it first increased and then decreased for the copper-alumina composite materials. The wear loss of the copper-alumina composite materials is always lower than that of copper. The highest relative wearability is 3.13, indicating better wear resistance. The wear mechanism of copper is oxidation wear, whereas that for the copper-alumina composite materials is adhesive wear.