首页> 中文期刊> 《结构化学》 >A Novel 3D Zn-La Heterometallic Coordination Polymer Involving in situ Glycinate Ligand Synthesis

A Novel 3D Zn-La Heterometallic Coordination Polymer Involving in situ Glycinate Ligand Synthesis

         

摘要

One novel 3D 3d-4f coordination polymer, [LaZn(glc)(ox)2(H20)2]n (1, glc = glycinate, ox = oxalate), was obtained by the in situ synthesis of glycinate from the reaction of tetrazole-l-acetic acid, sodium oxalate, zinc nitrate and lanthanide oxide in the presence of a trace quantity of nitric acid under hydrothermal conditions. Compound 1 is of monoclinic, space group P21 with a = 0.99601(9), b = 1.14592(10), c = 1.19107(10) nm and β = 108.7150(10)°. 1 exhibits an unusual 3D heterometallic coordination framework constructed by heterometallic dinuclear LaZn subunits and mixed ox and glc linkers with a uninodal 6-connected vine {33.43.58.6} net.

著录项

  • 来源
    《结构化学》 |2012年第10期|1429-1434|共6页
  • 作者单位

    College of Science, Guangdong Ocean University, Zhanjiang 524088, China;

    College of Environment Science and Engineering, Donghua University, Shanghai 200051, China;

    College of Environment Science and Engineering, Donghua University, Shanghai 200051, China Chinese and American Institute for Genetic Nutrition and HealthResearch, Guangdong Medical College, Zhanjiang 524023, China;

    College of Food Science and Technology,Guangdong Ocean University, Zhanjiang 524088, China;

    College of Environment Science and Engineering, Donghua University, Shanghai 200051, China;

    College of Food Science and Technology,Guangdong Ocean University, Zhanjiang 524088, China;

    College of Food Science and Technology,Guangdong Ocean University, Zhanjiang 524088, China;

    Department of Chemistry, University of Malaya, Kuala Lumpur 50603, Malaysia;

  • 原文格式 PDF
  • 正文语种 chi
  • 中图分类 金属-非金属复合材料;
  • 关键词

    异金属配位聚合物; 原位合成; 氨基乙酸; 硝酸锌; 香格里拉; 配体; 3D; 镧系元素;

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号