首页> 外国专利> Purification treatment for iron composite particles of soil and groundwater that has been contaminated with organic halogen compounds, to a process for the preparation thereof, the iron purification agent comprising the composite particles, their preparation and purification treatment of soil and groundwater that has been contaminated with organic halogen compounds way

Purification treatment for iron composite particles of soil and groundwater that has been contaminated with organic halogen compounds, to a process for the preparation thereof, the iron purification agent comprising the composite particles, their preparation and purification treatment of soil and groundwater that has been contaminated with organic halogen compounds way

机译:已被有机卤素化合物污染的土壤和地下水的铁复合颗粒的净化处理及其制备方法,包括该复合颗粒的铁净化剂,它们的制备和已被有机污染物污染的土壤和地下水的净化处理有机卤素化合物的方式

摘要

PPROBLEM TO BE SOLVED: To provide a purifying agent for efficiently and lastingly treating an aliphatic organohalogen compound or an aromatic halogen compound contained in soil or ground water to reduce the load applied to environment to the utmost. PSOLUTION: An iron composite particulate powder for purifying soil or ground water polluted with the organohalogen compound is suppressed in the elution of impurities and contains 30 to 99 wt% of -Fe. This iron composite particulate powder is obtained by a method wherein a suspension containing a ferrous salt-containing precipitate, which is obtained by adding an alkali hydroxide or alkali carbonate aqueous solution to a purified aqueous solution containing a ferrous salt, is oxidized to obtain a goethite particulate powder, this goehthite particulate power or a hematite particulate powder obtained by dehydrating the goehthite particulate powder under heating is reduced under heating to produce an iron particulate powder which is, in turn, taken out into water without forming a surface oxidized film on the iron particulate powder in a gaseous phase and the surface oxidized film is subsequently formed on the surfaces of the particle of the iron particulate powder in water before the iron particulate powder is dried. PCOPYRIGHT: (C)2004,JPO
机译:<要解决的问题:提供一种净化剂,用于有效和持久地处理土壤或地下水中所含的脂肪族有机卤素化合物或芳香族卤素化合物,以最大程度地减少对环境的负荷。

解决方案:一种用于净化被有机卤素化合物污染的土壤或地下水的铁复合颗粒粉末,其杂质洗脱受到抑制,并且含有30至99 wt%的-Fe。该铁复合颗粒粉末通过以下方法获得:将包含含亚铁盐的沉淀物的悬浮液氧化,该悬浮液是通过将碱金属氢氧化物或碱金属碳酸盐水溶液添加到含亚铁盐的纯化水溶液中而获得的,从而得到针铁矿。颗粒粉末,该针铁矿颗粒粉末或通过加热使针铁矿颗粒粉末脱水而获得的赤铁矿颗粒粉末在加热下被还原以产生铁颗粒粉末,该铁颗粒粉末又被带入水中而未在铁上形成表面氧化膜然后,在将铁颗粒粉末干燥之前,在水中的铁颗粒粉末的颗粒表面上形成气相氧化颗粒粉末和表面氧化膜。

版权:(C)2004,日本特许厅

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