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首页> 外文期刊>Physica status solidi, B. Basic research >Kondo effect in oscillating molecules
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Kondo effect in oscillating molecules

机译:振荡分子的近藤效应

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We consider electronic transport through break-junctionsbridged by a single molecule in the Kondo regime. We de-scribe the system by a two-channel Anderson model. We takethe tunneling matrix elements to depend on the position of themolecule. It is shown, that if the modulation of the tunnelingby displacement is large, the potential confining the moleculeto the central position between the leads is softened and theposition of the molecule is increasingly susceptible to externalperturbations that break the inversion symmetry. In this regime,the molecule is attracted to one of the leads and as a conse-quence the conductance is small. We argue on semi-classicalgrounds why the softening occurs and corroborate our findingsby numerical examples obtained by Wilson's numerical renor-malization group and Schonhammer-Gunnarsson's Variationalmethod. Sketch of the model device. The overlap integrals between themolecular orbital and the leads (V_L, V_Rfor left, right lead, re-spectively) are modulated by the position of the molecule. Theenergy of the molecular level ∈is determined by the gate volt-age.
机译:在近藤政权中,我们考虑通过单个分子桥接的断裂结进行电子传输。我们通过两个通道的Anderson模型来描述系统。我们采用隧穿矩阵元素取决于分子的位置。可以看出,如果通过位移对隧穿的调制较大,则将分子限制在引线之间的中心位置的电势会变软,并且分子的位置越来越容易受到破坏反演对称性的外部干扰的影响。在这种情况下,分子被吸引到其中一根导线上,因此电导很小。我们通过半经典的理由来论证为什么会发生软化,并通过威尔逊的数值再规范化小组和肖纳默-贡纳森的变分方法获得的数值实例来证实我们的发现。模型设备的草图。分子轨道与导线之间的重叠积分(分别为左,右导线的V_L,V_R)由分子的位置调节。分子能级ε的能量由栅极电压确定。

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