The Synthesis of P-1-[11-(Anthracen-9-ylmethoxy)undecyl]-P-2-(2-Acetamido-2-Deoxy-alpha-D-glucopyranosyl) Diphosphate and the Study of Its Acceptor Properties in the Enzymatic Reaction Catalyzed by a D-Rhamnosyltransferase from Pseudomonas aeruginosa

摘要

P-1-[11-(anthracen-9-ylmethoxy)undecyl]-P-2-(2-acetamido-2-deoxy-alpha-D-glucopyranosyl) diphosphate, a fluorescent derivative of undecyl diphosphate 2-acetamido-2-deoxyglucose, was chemically synthesized. The ability of the compound to serve as acceptor substrate for the transfer of D-rhamnose residue by D-rhamnosyltransferase WbpZ from Pseudomonas aeruginosa PAO1 was demonstrated.