Experimental controls on D/H and ~(13)C/~(12)C ratios of kerogen, bitumen and oil during hydrous pyrolysis

摘要

Large isotopic transfers between water-derived hydrogen and organic hydrogen occurred during hydrous pyrolysis experiments of immature source rocks, in spite of only small changes in organic ~(13)C/~(12)C. Experiments at 330 deg C over 72 h using chips or powder containing kerogen types I and III identify the rock/water ratio as main factor affecting #DELTA##delta#D for water and organic hydrogen. Our data suggest that larger rock permeability and smaller rock grain size increase the H-isotopic transfer between water-derived hydrogen and thermally maturing organic matter. Increasing hydrostatic pressure may have a similar effect, but the evidence remains inconclusive.