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Dissipation and oscillatory solvation forces in confined liquids studied by small-amplitude atomic force spectroscopy

机译:小幅度原子力谱研究密闭液体中的耗散和振荡溶剂化力

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摘要

We determine conservative and dissipative tip-sample interaction forces from the amplitude and phase response of acoustically driven atomic force microscope (AFM) cantilevers using a non-polar model fluid (octamethylcyclotetrasiloxane, which displays strong molecular layering) and atomically flat surfaces of highly ordered pyrolytic graphite. Taking into account the base motion and the frequency-dependent added mass and hydrodynamic damping on the AFM cantilever, we develop a reliable force inversion procedure that allows for extracting tip-sample interaction forces for a wide range of drive frequencies. We systematically eliminate the effect of finite drive amplitudes. Dissipative tip-sample forces are consistent with the bulk viscosity down to a thickness of 2-3 nm. Dissipation measurements far below resonance, which we argue to be the most reliable, indicate the presence of peaks in the damping, corresponding to an enhanced 'effective' viscosity, upon expelling the last and second-last molecular layer.
机译:我们使用非极性模型流体(八甲基环四硅氧烷,显示出很强的分子分层)和原子序平坦的热解表面,通过声驱动原子力显微镜(AFM)悬臂的振幅和相位响应来确定保守的和耗散的尖端样品相互作用力石墨。考虑到AFM悬臂上的基本运动以及与频率有关的附加质量和流体动力阻尼,我们开发了一种可靠的力反演程序,该程序可提取各种驱动频率下的尖端样本相互作用力。我们系统地消除了有限的驱动振幅的影响。耗散的尖端样品力与低至2-3 nm的体积粘度一致。远远低于共振的耗散测量值(我们认为是最可靠的)表明,在排出最后一个和第二个最后一个分子层时,阻尼中存在峰值,对应于增强的“有效”粘度。

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