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A scanning tip electrospinning source for deposition of oriented nanofibres

机译:用于沉积定向纳米纤维的扫描尖端电纺源

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摘要

We present a method for controlled deposition of oriented polymeric nanofibres. The method uses a microfabricated scanned tip as an electrospinning source. The tip is dipped in a polymer solution to gather a droplet as a source material. A voltage applied to the tip causes the formation of a Taylor cone, and at sufficiently high voltages, a polymer jet is extracted from the droplet. By moving the source relative to a surface, acting as a counter-electrode, oriented nanofibres can be deposited and integrated with microfabricated surface structures. For example, we deposited fibres of polyethylene oxide with diameters ranging from 100 to 1800 nm, with the diameter primarily depending on the concentration of the polymeric solution. In addition to the uniform fibre deposition, the scanning tip electrospinning source can produce self-assembled composite fibres of micro- and nanoparticles aligned in a polymeric fibre. We also deposited oriented conductive polymeric fibres of polyaniline and investigated the conductivity of these fibres as components for polymeric nanoelectronics.
机译:我们提出了一种方法来控制沉积的定向聚合物纳米纤维的沉积。该方法使用微细加工的扫描尖端作为静电纺丝源。将尖端浸入聚合物溶液中以收集液滴作为源材料。施加到尖端的电压导致形成泰勒锥,并且在足够高的电压下,从液滴中提取出聚合物射流。通过相对于作为反电极的表面移动光源,可以沉积取向的纳米纤维并将其与微加工的表面结构集成在一起。例如,我们沉积了直径范围从100到1800 nm的聚环氧乙烷纤维,其直径主要取决于聚合物溶液的浓度。除了均匀的纤维沉积之外,扫描头静电纺丝源还可以产生在聚合物纤维中排列的微米和纳米颗粒的自组装复合纤维。我们还沉积了聚苯胺的定向导电聚合物纤维,并研究了这些纤维作为聚合物纳米电子元件的导电性。

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