New bosonic excitation operators in many-electron wave functions

摘要

New excitation operators which have perfect bosonic symmetry are constructed for many-electron wave functions by regarding the system of many electrons as that of many species of bosons. Any electronic configurations can be generated by the new bosonic "void" operators. A coherent slate is constructed with the bosonic operators and is adopted as a trial function for the time-dependent variational principle. The equation of motion which has exactly the same form as Hamilton's equation in classical mechanics is obtained with the complex variational parameters, the number of which is equal to the number of electrons. (C) 1998 John Wiley & Sons, Inc. [References: 9]