Electronic structure and magnetic properties of Ce5CuPb3

摘要

We report on the magnetic and electronic transport properties and as well band electronic structure of the Ce5CuPb3 intermetallic compound, crystallizing in the hexagonal Hf5CuSn3-type structure. The magnetic and XPS data indicate localized character of the 4f-electrons. Ce5CuPb3 is shown to be a magnet with double transitions below T-C1, = 46 K and T-C2 = 5 K. Despite being magnetic the compound is found to have a strongly enhanced electronic specific heat (about 50mJ/mol Ce K-2). The electronic band Structure calculations based on TB-LMTO and FP-LAPW confirm the magnetic,round state. From the theoretical data we would expect that the Ce1 and Ce2 atoms located at the 4d and 6g, respectively, give distinct contributions to the density of states at the Fermi level. (C) 2007 Elsevier Inc. All rights reserved.