Magnetic study of two isotypic manganese chloro-sulfides: MnSbS2Cl and the new compound MnBiS2Cl

摘要

Among the MnPnQ(2)X compounds (Pn: pnictide; Q: chalcogen; X. halogen), two isotypic chloro-sulfides, MnSbS2Cl and MnBiS2Cl, have been studied. MnBiS2Cl is a new compound synthesized by solid state reaction at 500 degrees C. It is orthorhombic, space group Pnma, with a=9.502(2), b=3.8802(8), c=12.305(3) angstrom, V=453.7(2) angstrom(3), Z=4. Its X-ray single crystal study shows (001) waved layers of MnS4Cl2 octahedra, opposite edge-sharing along b, and corner-sharing along a. Similar magnetic susceptibilities for both compounds have been recorded, indicating high spin Mn2+ with anti-ferro magnetic exchange. Correlatively, specific heat versus temperature shows a magnetic transition at T-N=35 K for the Sb-bearing compound, and a two-steps magnetic transition at 28 and 32 K for the Bi isotype. The magnetic structure of MnSbS2Cl has been determined by neutron diffraction, revealing a magnetic ordering at 1.5 K with an incommensurate wave-vector along b (k=[0, 0.3838, 0]). Two modulation models, sinusoidal and helicoidal, give quite equivalent reliability factors (R-mag=0.0573 and 0.0586, respectively). (C) 2005 Elsevier Inc. All rights reserved.