Photoluminescence of (phanephos)tricarbonylrhenium(I) chloride with phanephos = 4,12-bis(diphenylphosphino)-[2.2]-paracyclophane

Horst Kunkely; Arnd Vogler

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Photoluminescence of (phanephos)tricarbonylrhenium(I) chloride with phanephos = 4,12-bis(diphenylphosphino)-[2.2]-paracyclophane

机译：氯化（phanephos）三羰基hen（I）与phanephos = 4,12-双（二苯基膦基）-[2.2]-对环环烷的光致发光

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The complex (phanephos)Re~I(CO)_3Cl with phanephos = 4,12-bis(diphenylphosphino)-[2.2]-paracyclophane is characterized by a lowest-energy intraligand (IL) excited state of the 2,2-paracyclophane moiety. This IL transition appears at #lambda#_(max) = 340 nm in absorption and at 383 (fluorescence) and 480 nm (phosphorescence, at r.t.) in emission.

机译：phanephos = 4,12-bis（diphenylphosphino）-[2.2] -paracyclophane的复合物（phanephos）Re〜I（CO）_3Cl的特征在于2,2-paracyclophane部分的最低能量内配体（IL）激发态。该IL跃迁出现在吸收的λλ（max）＝ 340nm处，并且在发射出现在383（荧光）和480nm（在rt处的磷光）。

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来源
《Inorganic Chemistry Communications》 |2002年第6期|共4页
作者
Horst Kunkely; Arnd Vogler;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
electronic spectra; luminescnece; rhenium complexes; cyclophane;

机译：电子光谱;发光度;r配合物;环烷;

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1. Photoluminescence of (phanephos)tricarbonylrhenium(I) chloride with phanephos = 4,12-bis(diphenylphosphino)-[2.2]-paracyclophane [J] . Horst Kunkely, Arnd Vogler Inorganic Chemistry Communications . 2002,第6期

机译：氯化（phanephos）三羰基hen（I）与phanephos = 4,12-双（二苯基膦基）-[2.2]-对环环烷的光致发光
2. Kinetic resolution of rac-4,12-dibromo[2.2]paracyclophane in a qpalladium [2.2]PHANEPHOS catalyzed amination [J] . Kai Rossen, Philip J.Pye, Ashok Maliakal The Journal of Organic Chemistry . 1997,第19期

机译：钯[2.2] PHANEPHOS催化胺化过程中rac-4,12-二溴[2.2]对环环烷的动力学拆分
3. Photoluminescence of [2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl]-tricarbonylrhenium (I)chloride origiginating from an MLCT excited state [J] . Kunkely Horst, Vogler Arnd Inorganic Chemistry Communications . 1999,第0期

机译：由MLCT激发态产生的[2,2'-双-（二苯基膦基）-1,1'-联萘基]-三羰基hen（I）的光致发光
4. NIR photoluminescence of Bi+ impurity center in RbY2Cl7 ternary chloride crystal [C] . A. N. Romanov, D. N. Vtyurina, E. V. Haula, International Conference Laser Optics . 2016

机译：RbY2Cl7三元氯化物晶体中Bi +杂质中心的NIR光致发光
5. Planar Chiral 2.2Paracyclophane-Based Bisoxazoline Ligands and Their Applications in Cu-Mediated N–H Insertion Reaction [O] . Daniel M. Knoll, Yuling Hu, Zahid Hassan, 2019

机译：平面手性2.2环芳基的双恶唑啉配体及其在Cu介导的NH插入反应中的应用
6. 4,12-Bis(2,2-dibromovinyl)[2.2]paracyclophane [O] . Clément, Sébastien, Guyard, Laurent, Knorr, Michael, 2009

机译：4,12-双（2,2-二溴乙烯基）[2.2]对环烷

Photoluminescence of (phanephos)tricarbonylrhenium(I) chloride with phanephos = 4,12-bis(diphenylphosphino)-[2.2]-paracyclophane

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