Photofunctional ternary rare earth (Eu~(3+), Tb~(3+), and Sm~(3+)) hybrid xerogels with hexafluoroacetylacetonate derived building block and bis(2-methoxyethyl)ether through coordination bonds

Bing Yan; Yan-Yan Li; Lei Guo

首页> 外文期刊>Inorganic Chemistry Communications >Photofunctional ternary rare earth (Eu~(3+), Tb~(3+), and Sm~(3+)) hybrid xerogels with hexafluoroacetylacetonate derived building block and bis(2-methoxyethyl)ether through coordination bonds

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Photofunctional ternary rare earth (Eu~(3+), Tb~(3+), and Sm~(3+)) hybrid xerogels with hexafluoroacetylacetonate derived building block and bis(2-methoxyethyl)ether through coordination bonds

机译：具有六氟乙酰丙酮酸酯结构单元和双（2-甲氧基乙基）醚通过配位键的光功能三元稀土（Eu〜（3 +），Tb〜（3+）和Sm〜（3+））杂合干凝胶

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Hexafluoroacetylacetonate (HFAA) is functionalized with 3-(triethoxysilyl)-propyl isocyanate (TEPIC) to achieve a new molecular building block HFAASi. Then two series ternary hybrid xerogels of rare earth ions (Eu~(3+), Tb~(3+), and Sm~(3+)) with HFAASi and special terminal ligands bis(2-methoxyethyl)ether (BME) have been assembled through coordination bonds, whose photoluminescence are studied in details.

机译：六氟乙酰丙酮酸酯（HFAA）与3-（三乙氧基甲硅烷基）-丙基异氰酸酯（TEPIC）官能化，以实现新的分子构件HFAASi。然后，稀土离子（Eu〜（3 +），Tb〜（3+）和Sm〜（3+））与HFAASi和特殊的末端配体双（2-甲氧基乙基）醚（BME）形成两个三元杂化干凝胶。通过配位键组装，详细研究了其光致发光。

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来源
《Inorganic Chemistry Communications》 |2011年第6期|共3页
作者
Bing Yan; Yan-Yan Li; Lei Guo;
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正文语种 eng
中图分类无机化学;
关键词
Ternary rare earth hybrid xerogel; Hexafluoroacetylacetonate building block; bis(2-methoxyethyl)ether; Photoluminescence;

机译：三元稀土杂化干凝胶;六氟乙酰丙酮结构单元;双（2-甲氧基乙基）醚;光致发光;

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1. Photofunctional ternary rare earth (Eu~(3+), Tb~(3+), and Sm~(3+)) hybrid xerogels with hexafluoroacetylacetonate derived building block and bis(2-methoxyethyl)ether through coordination bonds [J] . Bing Yan, Yan-Yan Li, Lei Guo Inorganic Chemistry Communications . 2011,第6期

机译：具有六氟乙酰丙酮酸酯结构单元和双（2-甲氧基乙基）醚通过配位键的光功能三元稀土（Eu〜（3 +），Tb〜（3+）和Sm〜（3+））杂合干凝胶
2. Novel photofunctional multicomponent rare earth (Eu~(3+), Tb ~(3+), Sm~(3+) and Dy~(3+)) hybrids with double cross-linking siloxane covalently bonding SiO_2/ZnS nanocomposite [J] . Yan B., Zhao Y., Li Y.-J. Photochemistry and Photobiology: An International Journal . 2011,第4期

机译：具有双交联硅氧烷共价键合SiO_2 / ZnS纳米复合材料的新型光功能多组分稀土（Eu〜（3 +），Tb〜（3 +），Sm〜（3+）和Dy〜（3+））杂化物
3. Photophysical properties of rare earth (Eu~(3+), Sm~(3+), Tb~(3+)) complex covalently immobilized in hybrid Si-O-B xerogels [J] . Wang C., Yan B. Journal of Fluorescence . 2011,第3期

机译：杂化Si-O-B干凝胶共价固定的稀土（Eu〜（3 +），Sm〜（3 +），Tb〜（3+））配合物的光物理性质
4. Recovery of red (Y{sub}2O{sub}3:Eu{sup}(3+)), Blue (Sr,Ca,Ba){sub}10(PO{sub}4){sub}6 Cl{sub}2:Eu{sup}(2+) and green (LaPO{sub}4:Tb{sup}(3+),Ce{sup}(3+)) rare earth phosphors from waste phosphor sludge by liquid/liquid extraction [C] . Mei Guangjun, Xie Kefeng International Conference on Bioinformatics and Biomedical Engineering . 2008

机译：恢复红色（y {sub} 2o {sub} 3：eu {sup}（3+）），蓝色（sr，ca，ba）{sub} 10（po {sub} 4）{sub} 6 cl {sub 2：欧盟{sup}（2+）和绿色（Lapo {sub} 4：tb {sup}（3 +），ce {sup}（3+））通过液/液萃取来自废磷光体污泥的稀土磷光体
5. Preparation of rare earth (europium(3+), terbium(3+), thulium(3+), and ytterbium(3+)) doped yttrium oxide luminescent ceramics by the use of reverse micelles. [D] . Corral, Jessica Olga. 2005

机译：通过使用反胶束制备稀土（eur（3 +），b（3+），th（3+）和y（3+））掺杂的氧化钇发光陶瓷。
6. Binary and Ternary Heterometallic (La³⁺, Gd³⁺, Y³⁺)–Eu³⁺ Functionalized SBA-15 Mesoporous Hybrids: Chemically Bonded Assembly and Photoluminescence [O] . Yan Bing, Kong Li-Li 2010

机译：二元和三元异金属（La ^{3 + ，Gd ^{3 + ，Y ^{3 + ）＆＃8211; Eu ^{3 + 功能化sBa-15介孔杂化材料：化学键合组装和光致发光}}}}

Photofunctional ternary rare earth (Eu~(3+), Tb~(3+), and Sm~(3+)) hybrid xerogels with hexafluoroacetylacetonate derived building block and bis(2-methoxyethyl)ether through coordination bonds

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