Solvent/C_(60) exchange on Ir(CO)(PPH3)2(Cl)(η2-C_(60)) and solvent/solvent' exchange on Ir(CO)(PPH3)2(Cl)(solvent)

摘要

Dissociation of C_(60) from Ir(CO)(PPh3)2(Cl)(η2-C_(60)) in a binary mixture of solvents (solvent, and solvent2) produced non-equilibrium mixtures of Ir(CO)(PPh3)2(Cl)(solvent1) and Ir(CO)(PPh3)2(Cl)(solvent2). Once the solvated species were produced, they underwent a relative fast solvent exchange between them to produce an equilibrium mixture.