Synthesis, characterization and crystal structure of a novel co-ordination polymer [Co(BTB)2(NCS)2]_n

摘要

A novel polymeric cobalt(II) complex with flexible ligand, [Co(BTB)2(NCS)2]_n 1 {BTB = 1,4-bis(1,2,4-tria-zol-1-yl)butane} has been prepared and structurally characterized by single-crystal X-ray diffraction as well as with elemental analysis, infrared spectroscopy and thermogravimetric analysis. The complex 1 consists of two discrete constituents, A and B, with the same chemical formula [Co(BTB)2(NCS)2] but different connecting mode. The six-co-ordination of Co~(2+) in A and B is in a distorted octahedral environment formed by four nitrogen atoms of the triazoles and two nitrogen atoms from two trans thiocyanato ligands. The structures of A and B demonstrate a one-dimensional neutral looped chain through two BTB-bridges and a two-dimensional network in which four BTB bridge four Co(II) atoms, respectively. A and B interpenetrate in an inclined fashion. The flexible BTB ligand exhibits three different configurations in 1.