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Self-assembly and crystal structure of a barium sulfonate chrysin coordination polymer

机译:磺酸钡菊花链配体聚合物的自组装和晶体结构

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摘要

A novel barium coordination polymer [Ba(C_(15)H_9O_7S)_2]_n was obtained by the self-assembly of Ba(II) with a sulfonate derivative of chrysin(5,7-bihydroxyflavone-6-sulfonate).The coordination polymer was characterized by single-crystal X-ray diffraction.Its bar-ium(II) atom is in distorted dodecahedron environment of 10 oxygen atoms.The coordination interaction,hydrogen bond and pi-pi stacking lead to the formation of a 1D chain structural coordination polymer.
机译:新型钡配位聚合物[Ba(C_(15)H_9O_7S)_2] _n是通过Ba(II)与菊花素的磺酸盐衍生物(5,7-联羟基黄酮-6-磺酸盐)自组装而获得的。用单晶X射线衍射对其进行表征,其钡(II)原子处于十个氧原子的十二面体畸变环境中,配位相互作用,氢键和π-π堆积导致形成一维链结构配位聚合物。

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