首页> 外文期刊>Inorganic Chemistry Communications >Novel chains constructed from heterotrinuclear units and l1,2-bis(4-pyridyl)ethane formulated as [M2M'(O2CPh)6](bpa) (M = Co, Zn, M' = Co, Cd): Their catalytic activity
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Novel chains constructed from heterotrinuclear units and l1,2-bis(4-pyridyl)ethane formulated as [M2M'(O2CPh)6](bpa) (M = Co, Zn, M' = Co, Cd): Their catalytic activity

机译:由杂三核单元和配制成[M2M'(O2CPh)6](bpa)的11,2-双(4-吡啶基)乙烷构成的新型链(M = Co,Zn,M'= Co,Cd):它们的催化活性

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摘要

Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M'(O2CC6H5]_n(bpa)_n(bpa= 1,2-bis(4-pyridyl)ethane, M2M' = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear hetero-nuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them.
机译:包含两个桥联配体bpa和苯甲酸酯的三种新型杂金属配合物,配制成[M2M'(O2CC6H5] _n(bpa)_n(bpa = 1,2-双(4-吡啶基)乙烷,M2M'= Zn2Co(1),Zn2Cd(已合成2)和Co2Cd(3)),这三种化合物均显示一维结构,其中包含通过桥接bpa配体连接的线性异核配位单元,化合物1-3的反应研究酯显示它们非常有效,其中2种是最好的。

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