Synthesis of a fluorescent gold(I)complex with a thiosemicarbazone,[Au2(3-NO2-Hbtsc)4]Cl2·2CH3CN

Tarlok S.Lobana; Sonia Khanna; Ray J.Butcher

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Synthesis of a fluorescent gold(I)complex with a thiosemicarbazone,[Au2(3-NO2-Hbtsc)4]Cl2·2CH3CN

机译：硫代半碳carb [Au2（3-NO2-Hbtsc）4] Cl2·2CH3CN荧光金（I）配合物的合成

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Direct reaction of gold(I)chloride with 3-nitrobenzaldehyde thiosemicarbazone(3-NO2-Hbtsc)in the presence of triphenylphosphine in acetonitrile has yielded ionic complex,[Au2(3-NO2-Hbtsc)4]Cl2·2CH3CN(1).It exhibited an intense fluorescence band(lambda_(em))at 383 nm(lambda_(ex)=300 nm),and two bands of medium intensity at 413 and 436 nm(lambda_(ex)=350 nm).Complex 1 represents first example of ionic gold(I)complex with a thiosemicarbazone.

机译：在三苯基膦的存在下，氯化金（I）与3-硝基苯甲醛硫代半脲（3-NO2-Hbtsc）在乙腈中直接反应，生成了离子络合物[Au2（3-NO2-Hbtsc）4] Cl2·2CH3CN（1）。它在383 nm（lambda_（ex）= 300 nm）处显示出很强的荧光带（lambda_（em）），在413和436 nm处显示了两个中等强度的谱带（lambda_（ex）= 350 nm）。离子金（I）与硫代半脲的络合物的例子。

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《Inorganic Chemistry Communications》 |2008年第12期|共3页
作者
Tarlok S.Lobana; Sonia Khanna; Ray J.Butcher;
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正文语种 eng
中图分类无机化学;
关键词
Gold(I); 3-Nitrobenzaldehyde thiosemicarbazone; 2D sheet structure; Fluorescence bands;

机译：金（I）;3-硝基苯甲醛硫半脲;二维片状结构;荧光带;

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1. Synthesis of a fluorescent gold(I)complex with a thiosemicarbazone,[Au2(3-NO2-Hbtsc)4]Cl2·2CH3CN [J] . Tarlok S.Lobana, Sonia Khanna, Ray J.Butcher Inorganic Chemistry Communications . 2008,第12期

机译：硫代半碳carb [Au2（3-NO2-Hbtsc）4] Cl2·2CH3CN荧光金（I）配合物的合成
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Synthesis of a fluorescent gold(I)complex with a thiosemicarbazone,[Au2(3-NO2-Hbtsc)4]Cl2·2CH3CN

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