首页> 外文期刊>Inorganic Chemistry Communications >Construction of isostructural Ln-Ag (Ln = Eu; Tb; Dy) nano-channel heterometallic coordination frameworks based on pyrazine-2-carboxylate and oxalate ligands
【24h】

Construction of isostructural Ln-Ag (Ln = Eu; Tb; Dy) nano-channel heterometallic coordination frameworks based on pyrazine-2-carboxylate and oxalate ligands

机译:基于吡嗪-2-羧酸盐和草酸盐配体的同构Ln-Ag(Ln = Eu; Tb; Dy)纳米通道异金属配位骨架的构建

获取原文
获取原文并翻译 | 示例
获取外文期刊封面目录资料

摘要

The self-assembly of pyrazine-2-carboxylate and oxalate with mixed-metal salts under hydrothermal conditions gave three isostructural 3D 4d-4f coordination polymers, LnAg(ox)(2-pzc)2 · H2O [Ln = Eu (1); Tb (2); Dy (3)] [ox = oxalate, 2-pzc = pyrazine-2-carboxylate]. All three structures exhibit same unusual 3D nanoporous heterometallic coordination frameworks constructed by zigzag lanthanide-oxalate chains and Ag(2-pzc)2 units. Furthermore, the luminescent properties of complexes t and 2 are discussed.
机译:在水热条件下吡嗪-2-羧酸盐和草酸盐与混合金属盐的自组装产生了三种同构的3D 4d-4f配位聚合物LnAg(ox)(2-pzc)2·H2O [Ln = Eu(1); b(2); Dy(3)] [ox =草酸盐,2-pzc =吡嗪-2-羧酸盐]。这三个结构都显示出相同的不寻常的3D纳米多孔异金属配位骨架,该骨架由之字形镧系元素草酸酯链和Ag(2-pzc)2单元构成。此外,讨论了配合物t和2的发光性质。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号