...
首页> 外文期刊>Inorganic Chemistry Communications >{[Cu2(μ-Cl)(μ-dppm)2](μ2-TCNQ)}_∞, a charge transfer compound derived from a donor with a copper dimer
【24h】

{[Cu2(μ-Cl)(μ-dppm)2](μ2-TCNQ)}_∞, a charge transfer compound derived from a donor with a copper dimer

机译:{[Cu2(μ-Cl)(μ-dppm)2](μ2-TCNQ)} _∞,一种来自施主的带有铜二聚体的电荷转移化合物

获取原文
获取原文并翻译 | 示例
           

摘要

The reaction of CuCl, dppm (bis(diphenylphosphino)methane), and TCNQ with a molar ratio set of 2:2:1 produced a one-dimensional compound 1 {[Cu2(μ-Cl)(μ-dppm)2](μ2-TCNQ)}_∞. Its structure was determined by X-ray crystallography. The new compound 1 was studied by IR and UV/Vis/NIR spectroscopy. 1 exhibits an intervalence transfer transition at λ=1296 nm, and also appears photoluminescence (λ_(max) = 818 nm) at room temperature.
机译:摩尔比为2:2:1的CuCl,dppm(双(二苯基膦基)甲烷)和TCNQ反应生成一维化合物1 {[[Cu2(μ-Cl)(μ-dppm)2]( μ2-TCNQ)} _∞。通过X射线晶体学确定其结构。通过IR和UV / Vis / NIR光谱研究了新化合物1。图1在λ= 1296nm处表现出间隔转移跃迁,并且在室温下也出现光致发光(λ_(max)= 818nm)。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号