A novel chiral 3D supramolecular framework based on organooxotin cluster

摘要

A novel triorganotin compound, namely [(Ph3Sn)3(CO3)(EtOH)3] · (ntb) · Cl · H2O (1), exhibits the novel chiral 3D supramolecular structure with a (10,3) topology based on the organooxotin cluster, in which ntb ligand and [(Ph3Sn)3(CO3)(EtOH)3]~+ unit act as three-connected nodes and link each other through O-H···N bonds.