An unexpected in situ formation of a substitute tetrazole ligand and its Mn(II) and Cu(II) complexes

摘要

The reaction of 2-aminomethylpyridine,benzaldehyde and NaN_3 in the presence of the metal ions leads to an unexpected in situ formation of a substituted tetrazole,5-(2-pyridyl)-1H-tetrazole,and its Mn(II) and Cu(II) compounds MnL_2(H_2O)_2 (1) and CuL_2(H_2O)_2 (2).In these structures,mononuclear units connect each other via hydrogen bonds to form a two-dimensional network.