Synthesis and structure of a bridging dimer of PhBi[O_2CCH(CH_3)CH_2ePh_3]_2

Lin Yu; Yong-Qiang Ma; Run-Chang Liu; Guo-Cang Wang; Jin-Shan Li

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Synthesis and structure of a bridging dimer of PhBi[O_2CCH(CH_3)CH_2ePh_3]_2

机译：PhBi [O_2CCH（CH_3）CH_2ePh_3] _2桥联二聚体的合成与结构

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摘要

The novel compound PhBi[O_2CCH(CH_3)CH_2GePh_3)]_2 has been synthesized and characterized structurally.The molecular structure shows that both carboxylates are bidentate ligands and oxygen bridges between symmetrically related molecules link them into dimer.

机译：合成并表征了新型化合物PhBi [O_2CCH（CH_3）CH_2GePh_3）] _ 2。分子结构表明，两种羧酸盐均为二齿配体，对称相关分子之间的氧桥将其连接成二聚体。

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来源
《Inorganic Chemistry Communications》 |2004年第3期|共2页
作者
Lin Yu; Yong-Qiang Ma; Run-Chang Liu; Guo-Cang Wang; Jin-Shan Li;
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正文语种 eng
中图分类无机化学;
关键词
bismuth; germanium; dimer; crystal structure;

机译：铋;锗;二聚体;晶体结构;

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1. Synthesis and structure of a bridging dimer of PhBi[O_2CCH(CH_3)CH_2ePh_3]_2 [J] . Lin Yu, Yong-Qiang Ma, Run-Chang Liu, Inorganic Chemistry Communications . 2004,第3期

机译：PhBi [O_2CCH（CH_3）CH_2ePh_3] _2桥联二聚体的合成与结构
2. ansa-Ytterbocene(III) chloride and borohydride with a short bridge and bulky substituents: synthesis and crystal structures of [meso-(CH_3)_2Si[3-(CH_3)_3SiC_5H_3]_2 Yb(#mu#_2-Cl)]_2 and meso-(CH_3)_2Si[3-(CH_3)_3SiC_5H_3]_2 Yb[(#mu#_2-H)_3BH](THF) [J] . A. V. Khvostov, V. V. Nesterov, B. M. Bulychev, Journal of Organometallic Chemistry . 1999,第2期

机译：具有短桥和大取代基的ansa-Ytterbocene（III）氯化物和硼氢化物：[meso-（CH_3）_2Si [3-（CH_3）_3SiC_5H_3] _2 Yb（＃mu＃_2-Cl）] _ 2和介孔-（CH_3）_2Si [3-（CH_3）_3SiC_5H_3] _2 Yb [（＃mu＃_2-H）_3BH]（THF）
3. Synthesis of Terminal and Bridging Acetonyl Complexes of Palladium(II). Crystal Structures of [{(AsPh_3)(C_6F_5)Pd}_2{#mu#-CH_2C(O)CH_3}_2], [(AsPh_3)(C_6F_5)Pd{CH_2C(O)CH_3}(t-BuNC)], and [(o-C_6H_4CH_2NMe_2)Pd{O,O'-CH(CO_2Et)_2}] [J] . Jose Ruiz, Venancio Rodriguez, Natalia Cutillas Organometallics . 2001,第10期

机译：钯（II）末端和桥联乙酰基配合物的合成。 [{（AsPh_3）（C_6F_5）Pd} _2 {＃mu＃-CH_2C（O）CH_3} _2]，[（AsPh_3）（C_6F_5）Pd {CH_2C（O）CH_3}（t-BuNC）的晶体结构，和[（o-C_6H_4CH_2NMe_2）Pd {O，O'-CH（CO_2Et）_2}]
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机译：分中性（CH_3）_2（C_2H_5）N〜+（CH_2）_NN〜+（C_2H_5）（CH_3）_2和（C_2H_5）_2-（CH_3）N〜+（CH_2）_NN〜+（CH_3）（C_2H_5）_2离子n = 4-6作为沸石合成中的结构引导剂
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Synthesis and structure of a bridging dimer of PhBi[O_2CCH(CH_3)CH_2ePh_3]_2

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