The first one-dimensional manganese polymer containing 4,5-dicarboxyimidazole:solvothermal synthesis,crystal structure and magnetic behavior of [Mn(phen)(Hdcbi)]_n (H_3dcbi=4,5-dicarboxyimidazole,phen= 1,10-phenanthroline)

Xiaofeng Zhang; Deguang Huang; Feng Chen; Changneng Chen; Qiutian Liu

首页> 外文期刊>Inorganic Chemistry Communications >The first one-dimensional manganese polymer containing 4,5-dicarboxyimidazole:solvothermal synthesis,crystal structure and magnetic behavior of [Mn(phen)(Hdcbi)]_n (H_3dcbi=4,5-dicarboxyimidazole,phen= 1,10-phenanthroline)

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The first one-dimensional manganese polymer containing 4,5-dicarboxyimidazole:solvothermal synthesis,crystal structure and magnetic behavior of [Mn(phen)(Hdcbi)]_n (H_3dcbi=4,5-dicarboxyimidazole,phen= 1,10-phenanthroline)

机译：第一种含4,5-二羧基咪唑的一维锰聚合物：溶剂热合成，[Mn（phen）（Hdcbi）] _ n（H_3dcbi = 4,5-二羧基咪唑，phen = 1,10-菲咯啉）的晶体结构和磁性

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Solvothermal reaction of Mn(OAc)2 (center dot)4H2O with 4,5-dicarboxyimidazole and phenanthroline resulted in a complex [Mn(phen)-(Hdcbi)]_n 1 in which Hdcbi as a mu_2-bridge links two neighboring manganese(II) ions in chelating mode,forming one-dimensional zigzag chain framework.The fitting of magnetic data (J=-0.11 cm~(-1),zJ'=-0.06 cm~(-1),g=2.01) indicates weak antiferro-magnetic coupling interactions between the Mn(II) sites.

机译：Mn（OAc）2（中心点）4H2O与4,5-二羧基咪唑和菲咯啉的溶剂热反应生成复杂的[Mn（phen）-（Hdcbi）] _ n 1，其中Hdcbi作为mu_2桥连接两个相邻的锰（ II）离子处于螯合模式，形成一维之字形链框架。磁数据的拟合（J = -0.11 cm〜（-1），zJ'=-0.06 cm〜（-1），g = 2.01）表明弱Mn（II）位点之间的反铁磁耦合相互作用。

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来源
《Inorganic Chemistry Communications》 |2004年第5期|共4页
作者
Xiaofeng Zhang; Deguang Huang; Feng Chen; Changneng Chen; Qiutian Liu;
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正文语种 eng
中图分类无机化学;
关键词
Solvothermal synthesis; Manganese complex; One-dimensional chain; Crystal structure; 4; 5-dicarboxyimidazole;

机译：溶剂热合成;锰配合物;一维链;晶体结构;4;5-二羧基咪唑;

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1. The first one-dimensional manganese polymer containing 4,5-dicarboxyimidazole:solvothermal synthesis,crystal structure and magnetic behavior of [Mn(phen)(Hdcbi)]_n (H_3dcbi=4,5-dicarboxyimidazole,phen= 1,10-phenanthroline) [J] . Xiaofeng Zhang, Deguang Huang, Feng Chen, Inorganic Chemistry Communications . 2004,第5期

机译：第一种含4,5-二羧基咪唑的一维锰聚合物：溶剂热合成，[Mn（phen）（Hdcbi）] _ n（H_3dcbi = 4,5-二羧基咪唑，phen = 1,10-菲咯啉）的晶体结构和磁性
2. Synthesis, crystal structure and catalytic activity for H2O2 disproportionation of the manganese(II) coordination polymer {[Mn(O2C(CF2)(8)CO2)(phen)(2)]H2O}(n) (phen=1,10-phenanthroline) [J] . Kani I, Darak C, Sahin O, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2008,第4期

机译：锰（II）配位聚合物{[Mn（O2C（CF2）（8）CO2）（phen）（2）] H2O}（n）（phen = 1,10-菲咯啉
3. Synthesis and fungitoxic activity of manganese(II) complexes of fumaric acid: X-ray crystal structures of [Mn(fum)(bipy)(H2O)] and [Mn(Phen)(2)(H2O)(2)] (fum)center dot 4H(2)O (fumH(2) =fumaric acid; bipy=2,2 '-bipyridine; phen=1,10-phenanthroline) [J] . Devereux M., Leon V., Geraghty M., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第10期

机译：富马酸锰（II）配合物的合成和杀真菌活性：[Mn（fum）（bipy）（H2O）]和[Mn（Phen）（2）（H2O）（2）]的X射线晶体结构）中心点4H（2）O（fumH（2）=富马酸; bipy = 2,2'-联吡啶; phen = 1,10-菲咯啉）
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）

The first one-dimensional manganese polymer containing 4,5-dicarboxyimidazole:solvothermal synthesis,crystal structure and magnetic behavior of [Mn(phen)(Hdcbi)]_n (H_3dcbi=4,5-dicarboxyimidazole,phen= 1,10-phenanthroline)

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