The first one-dimensional metal-organic coordination polymer with 4-quinolineacrboxylate as building block: [Cd(#mu#_2-H_2O)(4-quinolinecarboxyato-O,O)_2]

摘要

The hydro(solvo)thermal reaction of 4-quinolinecarbaldehyde with Cd(ClO_4)_2(centre dot)6H_2O yields a one-dimensional linear chain metal-organic coordination polymer with carboxylate-bridged and #mu#_2-OH_2:[Cd(#mu#_2-H_2O)(4-quinolinecarboxylato-O,O)_2] 1 which is characterized by single crystal X-ray determination and IR. Crystallographic data for 1, C_(20)H_(14)CdN_2O_5, monoclinic, space group C2/c, a = 15.368(2), b = 14.399(2), c = 7.7969(11) A, #beta# = 92.507(3) deg, Z = 4, V = 1723.7(4) A~3.