C-S bond cleavage by cobalt: synhesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments

Gudneppanavar Rajsekhar; Chebrolu P.Rao; PauliK.Saarenketo; Erkki Kolehmainen; Kari Rissanen

首页> 外文期刊>Inorganic Chemistry Communications >C-S bond cleavage by cobalt: synhesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments

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C-S bond cleavage by cobalt: synhesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments

机译：钴裂解C-S键：1,2-二-（邻-水杨基铝二氨基苯硫基）乙烷及其Co（III）产物的合成，表征及晶体结构测定，C-S键裂解的片段

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1,2-Di-(o-salicylaldiminophenylthio)ethane reacts with Co(II) salts to form a complex with oxidative cleavage of the C-S bond, to result in the formation of a Co(II) complex of the cleaved ligands.

机译：1,2-二-（邻-水杨基铝基二氨基苯硫基）乙烷与Co（II）盐反应形成C-S键的氧化裂解的络合物，从而形成裂解的配体的Co（II）络合物。

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《Inorganic Chemistry Communications》 |2002年第9期|共4页
作者
Gudneppanavar Rajsekhar; Chebrolu P.Rao; PauliK.Saarenketo; Erkki Kolehmainen; Kari Rissanen;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
1; 2-di-(o-salicylaldiminophenylthio)ethane; oxidative cleavage of C-S bond; crystal structure of Co(III); activation by Co(II) salts;

机译：1;2-二-（邻水杨基铝二氨基苯硫基）乙烷;C-S键的氧化裂解;Co（III）的晶体结构;Co（II）盐的活化;

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1. C-S bond cleavage by cobalt: synhesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments [J] . Gudneppanavar Rajsekhar, Chebrolu P.Rao, PauliK.Saarenketo, Inorganic Chemistry Communications . 2002,第9期

机译：钴裂解C-S键：1,2-二-（邻-水杨基铝二氨基苯硫基）乙烷及其Co（III）产物的合成，表征及晶体结构测定，C-S键裂解的片段
2. Comparative Study for the Cobalt(II)- and Iron(II)-Mediated Desulfurization of Disulfides Demonstrating That the C-S Bond Cleavage Step Precedes the S-S Bond Cleavage Step [J] . Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2020,第6期

机译：钴（II）的比较研究 - 和铁（II）介导的二硫化脱硫证明C-S键切割步骤在S-S键切割步骤之前
3. Shining Light on C-S Bonds: Recent Advances in C-C Bond Formation Reactions via C-S Bond Cleavage under Photoredox Catalysis [J] . Gao Jian, Feng Jie, Du Ding Chemistry, an Asian journal . 2020,第22期

机译：在C-S键上闪亮光：C-C键在Photoredox催化下通过C-C键形成反应的最新进展
4. Synthesis of 2,2’-Bis(methylthio)-1,1’-Biphenyl to Dibenzothiophenes via the Cleavage of Two C-S Bonds [C] . Yoshihiro Masuya, Yuki Kawashima, Hayato Fujimoto 日本化学会春季年会講演予稿集 . 2018

机译：通过两个C-S键的切割合成2,2'-BIS（甲硫基）-1,1'-联苯酯至二苯甲酸酯
5. Escherichia coli chorismate synthase: a deuterium kinetic-isotope effect under single-turnover and steady-state conditions shows that a flavin intermediate forms before the C-(6proR)-H bond is cleaved. [O] . S Bornemann, S Balasubramanian, J R Coggins, 1995

机译：大肠杆菌分支酸合酶：在单周转和稳态条件下的氘动力学同位素效应表明黄素中间体在C-（6proR）-H键断裂之前就形成了。
6. RhCl3-Assisted C-H and C-S Bond Scissions: Isomeric Self-Association of Organorhodium(III) Thiolato Complex. Synthesis, Structure, and Electrochemistry [O] . -1

机译：RHCL3辅助C-H和C-S粘合缩写：异构自我关联（III）硫醇复合物。合成，结构和电化学
7. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

C-S bond cleavage by cobalt: synhesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments

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