Tetrameric spin crossover iron(II) complex constructed by imidazole…chloride hydrogen bonds

Koshiro Nishi; Takeshi Fujinami; Aki Kitabayashi

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Tetrameric spin crossover iron(II) complex constructed by imidazole…chloride hydrogen bonds

机译：咪唑…氯化氢键构成的四聚体自旋交联铁（II）配合物

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A tetrameric spin crossover (SCO) Fe" complex was synthesized, and the structure and magnetic properties were studied. The tetrameric structure is constructed by four imidazole…Cl~ hydrogen bonds centered at one Cl~- ion. The compound showed an incomplete gradual SCO behavior due to intra-cluster "anticooperative-like" interaction.

机译：合成了四元自旋交联的Fe“配合物，研究了其结构和磁性。该四元结构由四个咪唑…Cl〜氢键为一个Cl〜-离子构成。该化合物显示出不完全的逐步SCO行为是由于集群内的“类似anticooper-like”的相互作用。

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《Inorganic Chemistry Communications》 |2011年第7期|共4页
作者
Koshiro Nishi; Takeshi Fujinami; Aki Kitabayashi;
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正文语种 eng
中图分类无机化学;
关键词
Iron; Spin crossover; Hydrogen bond; Imidazole;

机译：铁;自旋交叉;氢键;咪唑;

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1. Tetrameric spin crossover iron(II) complex constructed by imidazole…chloride hydrogen bonds [J] . Koshiro Nishi, Takeshi Fujinami, Aki Kitabayashi Inorganic Chemistry Communications . 2011,第7期

机译：咪唑…氯化氢键构成的四聚体自旋交联铁（II）配合物
2. 1D and 2D assembly structures by imidazole?chloride hydrogen bonds of iron(ii) complexes [Fe~(II)(HL~(n-Pr))_3] Cl·Y (HL~(n-Pr) = 2-methylimidazol-4-yl-methylideneamino-n- propyl; Y = AsF_6, BF_4) and their spin states [J] . Fujinami T., Nishi K., Matsumoto N., Dalton transactions: An international journal of inorganic chemistry . 2011,第45期

机译：铁（ii）配合物[Fe〜（II）（HL〜（n-Pr））_ 3]的咪唑氯化氢氢键构成的一维和二维组装结构Cl·Y（HL〜（n-Pr）= 2-甲基咪唑- 4-基-亚甲基氨基-正丙基; Y = AsF_6，BF_4）及其自旋态
3. Layered iron(II) spin crossover complex constructed by NH?Br - hydrogen bonds with 2 K wide thermal hysteresis, [Fe ~(II)H_3L~(Me)]Br·CF_3SO_3 (H_3L~(Me) = tris[2-(((2-methylimidazol-4-yl)methylidene) amino)ethyl]amine) [J] . Hagiwara H., Matsumoto N., Iijima S., Inorganica Chimica Acta . 2011,第1期

机译：由具有2 K宽热滞的NH？Br-氢键构成的层状铁（II）自旋交联络合物[Fe〜（II）H_3L〜（Me）] Br·CF_3SO_3（H_3L〜（Me）= tris [2-（（（2-甲基咪唑-4-基）亚甲基）氨基）乙基]胺）
4. Substituent Effect in Spin-Crossover Behavior of Iron(II)-Ar-pybox Complexes (Ar-pybox= 4-Aryl-2,6-bis(oxazolin-2-yl)pyridine) [C] . Akifumi Kimura, Takayuki Ishida Irago Conference . 2018

机译：铁（II）-AR-ubox络合物的旋转交叉行为中的取代基效应（Ar-pybox = 4-芳基-2,6-双（恶唑啉-2-基）吡啶）
5. Syntheses and solid-state structures of tris(pyrazolyl)methane complexes of iron(II) with unique spin-crossover behaviors and group 1 and 2 metals. [D] . Little, Christine Ann. 2001

机译：铁（II）的三（吡唑基）甲烷配合物的合成和固态结构，具有独特的自旋交叉行为以及第1和第2组金属。
6. Hydrogen Bonding Influence of 110-Phenanthroline on Five-Coordinate High-Spin Imidazole-Ligated Iron(II) Porphyrinates [O] . Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, -1

机译：110-菲咯啉对五配位高旋转咪唑连接的卟啉铁（II）氢键的影响
7. Supramolecular Spin-Crossover Iron Complexes Based on Imidazole- Imidazolate Hydrogen Bonds [O] . -1

机译：基于咪唑 - 咪唑酯氢键的超分子分子旋转铁复合物
8. Investigations of Selective Interactions of the Iron/Aqueous Sodium Chloride System. Part 1. The Adsorption of Chloride Ion by Alpha-Iron(III) Oxide in Sodium Chloride Solutions Saturated by Oxygen at 30C [R] . Kovacina, T. A., Venezky, D. L. 1971

机译：铁/氯化钠水溶液体系选择性相互作用的研究。第1部分。在30℃下氧气饱和的氯化钠溶液中α-铁（III）氧化物对氯离子的吸附

Tetrameric spin crossover iron(II) complex constructed by imidazole…chloride hydrogen bonds

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