Photoredox reactivity of iron(III) phenolates in aqueous solution induced by ligand-to-metal charge transfer excitation

摘要

Iron(III) complexes with phenolate ligands (m-cresolate and tyrosinate) undergo a redox photolysis in aqueous solution upon phenolate->Fe(III) ligand-to-metal charge transfer excitation.At lambda_irr=577 nm the quantum yields of Fe(II) formation are approximately PHI=10~(-4).