Novel Cd(II) and Co(II) 2-D frameworks based on terephthalate and 1-substitutedimidazole mixed-ligands

摘要

The two Cd(II) and Co(II) 2-D frameworks have been prepared by means of self-assemblies of Cd(II) or Co(II) salts and 1-substituted imidazole and terephthalic acid,and structurally characterized by X-ray diffraction analyses.In complex 1 2-D frameworks with rhombic cavity are formed,in which the each top point of rhombus contains one hexa and two heptacoordinated Cd(II).In complex 2 2-D networks with rectangular cavities are formed,and the opposite benzene rings from carboxyls in each rectangular cavity are parallel.