A three-dimensional porous metal-organic framework of unusual rob topology based on a novel fluorinated bis (imidazole) ligand

摘要

A unique 3-D open coordination framework based on a fluorinated bis(imidazole) ligand has been prepared and characterized, showing a six-connected self-penetrating network with rob (4~8.6~6.8) topology. Porosity of desolvated and resolvated samples was characterized by X-ray powder diffraction (XRPD).