A novel double-helical-chain coordination polymer constructed from 2,2'-biphenyldicarboxylate-linked binuclear-copper motif

摘要

The first 1-D double-helical-chain coordination polymer,[H_2O)Cu(BPDC)] (2,2'-biphenyldicarboxylate),based upon the binuclear square pyramidal copper(II)-pair motifs has been synthesized under hydrothermal conditions and characterized by single crystal X-ry diffraction technique.[(H_2O)Cu(BPDC)] crystallized in orthorhombic crystal system,space group Cmca with unit cell dimensions a=21.073(6) A,b=7.118(2) A and c=17.670(5) A,Z=8.