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首页> 外文期刊>Inorganic Chemistry Communications >Structures and magnetism of bimetallic octacyanometallates: honeycomb-like [Mo(CN)_8Ni_2(pn)_4]_n·4nH_2O and binuclear [Mo(CN)_8Ni(en)_2(H_2O)][Ni(en)_3·2H_2O (pn = 1,3-diaminopropane, en = 1,2-diaminoethane)
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Structures and magnetism of bimetallic octacyanometallates: honeycomb-like [Mo(CN)_8Ni_2(pn)_4]_n·4nH_2O and binuclear [Mo(CN)_8Ni(en)_2(H_2O)][Ni(en)_3·2H_2O (pn = 1,3-diaminopropane, en = 1,2-diaminoethane)

机译:双金属八氰基金属酸盐的结构和磁性:蜂窝状[Mo(CN)_8Ni_2(pn)_4] _n·4nH_2O和双核[Mo(CN)_8Ni(en)_2(H_2O)] [Ni(en)_3·2H_2O(pn = 1,3-二氨基丙烷,en = 1,2-二氨基乙烷)

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摘要

Bimetallic octacyanometallates [Mo(CN)_8Ni_2(pn)_4]_n·4nH_2O (1) and [Mo(CN)_8Ni(en)_2(H_2O)][Ni(en)_3]·2H_2O (2) based on [Mo(CN)_8]~(4-) were synthesizedin aqueous solution, and their crystal and molecular structures have been determined. The complex [Mo(CN)_8Ni_2(pn)_4]_n·4nH_2O (1) consists of novel two-dimensional honeycomb-like layers. The complex [Mo(CN)_8Ni(en)_2(H_2O)] [Ni(en)_3]·2H_2O (2) contains a binuclear anion [Mo(CN)_8Ni(en)_2(H_2O)]~(2-), [Ni(en)_3]~(2+) cation and two lattice water molecules. Magnetic studies suggest a possible weak antiferromagnetic interaction between Ni~(2+) ions in 1.
机译:基于[Mo]的双金属八氰基金属酸盐[Mo(CN)_8Ni_2(pn)_4] _n·4nH_2O(1)和[Mo(CN)_8Ni(en)_2(H_2O)] [Ni(en)_3]·2H_2O(2)在水溶液中合成了(CN)_8]〜(4-),并确定了它们的晶体和分子结构。复合物[Mo(CN)_8Ni_2(pn)_4] _n·4nH_2O(1)由新颖的二维蜂窝状层组成。复合物[Mo(CN)_8Ni(en)_2(H_2O)] [Ni(en)_3]·2H_2O(2)包含双核阴离子[Mo(CN)_8Ni(en)_2(H_2O)]〜(2- ),[Ni(en)_3]〜(2+)阳离子和两个晶格水分子。磁性研究表明1中的Ni〜(2+)离子之间可能存在弱的反铁磁相互作用。

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