Influence of upwelling Zechstein sulphate on the concentration and isotope signature of sedimentary sulphides in a fluvioglacial sand aquifer

摘要

Very low concentrations of total S, mainly sedimentary sulphides, were quantitatively extracted from Quaternary sands of the Elbe Basin, using HNO3, Br-2 and HCl, to distinguish 3 aquifer zones:an upper aerobic section, containing low concentrations (only a few ppm) of non-sulphidic S compounds,the central and lower part of the aquifer, dominated by S-34-depleted sedimentary Fe sulphides, formed by reduction of infiltrating SO4, derived from groundwater recharge, andthe lowest 5-10 m of the aquifer, containing high concentrations of S-34-enriched sulphides.The latter originated from dissolved Zechstein SO4, which was reduced during upwelling through the organic-rich Tertiary aquiclude. H2S and HS- reacted and precipitated with Fe and other metal ions shortly after migration into the C-org-poor Quaternary aquifer. The sulphides yield valuable information concerning the ascent of confined saline solutions from isolated Zechstein evaporites inside the "Muhlberger Graben", which is covered by Cenozoic sediments and whose extension and boundaries are therefore not well defined. Only a few locations, close to faults and geological windows, show deep-water admixture sufficiently strong to cause visible changes in hydrochemistry and isotopic ratios of SO4 and DIC directly above the base of the Quaternary. Sulphides showing different origins may possibly be used in other areas to provide information concerning underlying geology and hydrodynamics. (C) 2004 Elsevier Ltd. All rights reserved.