DABCO and DMAP-Why Are They Different in Organocatalysis?

Mahiuddin Baidya; Shinjiro Kobayashi; Frank Brotzel

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DABCO and DMAP-Why Are They Different in Organocatalysis?

机译：DABCO和DMAP-为什么它们的有机催化作用不同？

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1,4-Diazabicyclo[2.2.2]octane(DABCO,1),quinuclidine(2),and 4-(dimethylamino)pyridine(DMAP,Steglich's base,3)are important catalysts for a large variety of organic reactions.Attempts have been made to correlate the efficiency of organocatalysts with their Br0nsted basicities.

机译：1,4-二氮杂双环[2.2.2]辛烷（DABCO，1），喹啉（2）和4-（二甲基氨基）吡啶（DMAP，Steglich的碱，3）是用于多种有机反应的重要催化剂。我们将有机催化剂的效率与其布朗斯台德碱度相关联。

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《Angewandte Chemie》 |2007年第32期|共4页
作者
Mahiuddin Baidya; Shinjiro Kobayashi; Frank Brotzel;
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正文语种 eng
中图分类应用化学;
关键词
kinetics; linear free energy relationships nucleofugality; nucleophilicity; organocatalysis;

机译：动力学;线性自由能关系;核亲和性;亲核性;有机催化;

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1. DABCO and DMAP-Why Are They Different in Organocatalysis? [J] . Mahiuddin Baidya, Shinjiro Kobayashi, Frank Brotzel Angewandte Chemie . 2007,第32期

机译：DABCO和DMAP-为什么它们的有机催化作用不同？
2. The versatility of DABCO: synthetic applications of its basic, nucleophilic, and catalytic properties Part 4*. Ionic liquids and reagents (Selectfluor, DABSO) derived from DABCO, DABCO as piperazine source [J] . Chemistry of heterocyclic compounds . 2020,第3期

机译：DABCO的多功能性：其基本，亲核和催化性能部分4 *的合成应用。离子液体和试剂（Selectfluor，Dabso）衍生自Dabco，Dabco作为哌嗪来源
3. N-Arylation of DABCO with Diaryliodonium Salts: General Synthesis of N-Aryl-DABCO Salts as Precursors for 1,4-Disubstituted Piperazines [J] . Bugaenko Dmitry I, Yurovskaya Marina A., Karchava Alexander V Organic letters . 2018,第20期

机译：与二芳基碘盐的Dabco的N-芳基化：将N-芳基 - Dabco Salts的一般合成为1,4-二取代的哌嗪的前体
4. Catalytic Stereoselective Benzylic C-H Functionalizations by Oxidative C-H Activation and Organocatalysis [C] . Montse Guiteras Capdevila, Fides Benfatti, Luca Zoli European Symposium on Organic Chemistry . 2009

机译：催化立体选择性苄基C-H官能化氧化C-H活化与有机成分
5. Organocatalysis --- Hydrazine and Sulfonimide as New Functionalities in Asymmetric Organocatalysis. [D] . He, Hao. 2010

机译：有机催化-肼和磺酰亚胺是不对称有机催化的新功能。
6. Organocatalysis in heterocyclic synthesis: DABCO as a mild and efficient catalytic system for the synthesis of a novel class of quinazoline thiazolo 32-aquinazoline and thiazolo23-b quinazoline derivatives [O] . Haider Behbehani, Hamada Mohamed Ibrahim 2013

机译：杂环合成中的有机催化：DABCO作为温和高效的催化体系用于合成新型喹唑啉噻唑并32-a喹唑啉和噻唑并23-b喹唑啉衍生物
7. Organocatalysis in heterocyclic synthesis: DABCO as a mild and efficient catalytic system for the synthesis of a novel class of quinazoline, thiazolo 3,2-quinazoline and thiazolo2,3- quinazoline derivatives [O] . 2013

机译：杂环合成中的有机催化：DABCO是温和有效的催化体系，用于合成新型喹唑啉，噻唑并3,2-喹唑啉和噻唑并2,3-喹唑啉衍生物

DABCO and DMAP-Why Are They Different in Organocatalysis?

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