Photochemical and Radiolytic Production of an Organic Hydride Donor with a Ru~(II) Complex Containing an NAD+ Model Ligand

摘要

Nicotinamide adenine dinucleotide (NAD+) is one of the most important redox mediators in biological systems and acts as a reservoir/source of two electrons and a proton.The NAD+/NADH redox couple has been drawing much attention because bioinspired chemical reactions that produce neither high-energy intermediates nor unwanted by-products promise to be key factors in realizing sustainable energy sources.