Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles

Stepan Chuprakov; Frank W.Hwang; Vladimir Gevorgyan

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Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles

机译：Rh催化的炔丙基和腈对吡咯并三唑的环转移

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Transition-metal-catalyzed annulations are widely used in the synthesis of heterocyclic compounds.One of the most efficient methods for the construction of five-membered oxygen-containing heterocycles involves the annulation of diazocarbonyl compounds with alkynes and nitriles.

机译：过渡金属催化的环空反应广泛用于杂环化合物的合成中。构建五元含氧杂环的最有效方法之一是将重氮羰基化合物与炔烃和腈进行环化反应。

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《Angewandte Chemie》 |2007年第25期|共3页
作者
Stepan Chuprakov; Frank W.Hwang; Vladimir Gevorgyan;
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正文语种 eng
中图分类应用化学;
关键词
annulation; nitrogen heterocycles; rhodium synthetic methods; triazoles;

机译：环化;氮杂环;铑合成方法;三唑;

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1. Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles [J] . Stepan Chuprakov, Frank W.Hwang, Vladimir Gevorgyan Angewandte Chemie . 2007,第25期

机译：Rh催化的炔丙基和腈对吡咯并三唑的环转移
2. Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines [J] . Helan V., Gulevich A. V., Gevorgyan V. Chemical science . 2015,第3期

机译：需氧条件下铜催化吡啶并三唑与末端炔烃的环转移反应：吲哚嗪的有效合成
3. Cu-catalyzed transannulation reaction of pyridotriazoles with terminal alkynes under aerobic conditions: efficient synthesis of indolizines [J] . V. Helan, A. V. Gulevich, V. Gevorgyan Chemical science . 2015,第3期

机译：需氧条件下铜催化吡啶并三唑与末端炔烃的环转移反应：吲哚嗪的有效合成
4. Rh-Catalyzed Hydroboration of 1-Alkyne in the Presence of Amine. Theoretical Study of Active Species and Reaction Mechanism [C] . Akihiro Sugivama, Yuki Kuramoto, Yoshihide Nakao Symposium on Organometallic Chemistry . 2006

机译：在胺存在下1-炔的Rh催化水合氢化物。活性物质与反应机制的理论研究
5. Mechanistic evaluation of the nickel-catalyzed [2+2+2]-cycloaddition reaction of alkynes and nitriles. [D] . Stolley, Ryan Michael. 2014

机译：炔烃和腈的镍催化[2 + 2 + 2]-环加成反应的机理评价。
6. Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles [O] . Stepan Chuprakov, Frank W. Hwang, Vladimir Gevorgyan -1

机译：Rh催化的炔丙基和腈催化的吡咯并三唑的环转移
7. Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles. [O] . Stepan Chuprakov, Frank W. Hwang, Vladimir Gevorgyan 2007

机译：RH催化的吡啶二唑与炔烃和腈的转录。
8. Synthesis and X-ray Structure of a Zirconacyclopropene-Alkyne Complex: On theMechanism of Zirconium-Mediated Reductive Coupling of Alkynes [R] . Warner, B. P., Davis, W. M., Buchwald, S. L. 1993

机译：锆环丙烯 - 炔烃配合物的合成及X射线结构：锆介导的炔烃还原偶联机理研究

Rh-Catalyzed Transannulation of Pyridotriazoles with Alkynes and Nitriles

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