Structure and Magnetic Properties of a Decanuclear Oxoiron(II) Cluster: A Further Step to Understanding Iron Aggregation Processes

摘要

The hydrolysis of iron suits can be controlled by organic ligands so as to yield soluble molecular aggregates with nanometer dimensions, which can often be isolated in crystalline form and structurally, characterized. Though some work has been carriedout directly in aqueous environments, the use of nonaqueous media with a low water content has led to the synthesis of an unexpected variety of polvnuclear cluster.