Chiral Molecular Recognition by Aluminum Tris (2,6-diphenylphenoxide) in an Asymmetric 1,4-Addition

Susumu Saito; Hisashi Yamamoto; Hirotsugu Ito; Takashi Nagahara; Kazuaki Ishihara

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Chiral Molecular Recognition by Aluminum Tris (2,6-diphenylphenoxide) in an Asymmetric 1,4-Addition

机译：Tris（2,6-diphenylphenoxide）铝在不对称1,4-加成中的手性分子识别

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摘要

Asymmetric conjugate addition,the most popular reaction in organocopper chemistry,can be used to generated stereogenic centers,both stoichiometrically and catalytically.Recently there have been important advances i nthe strategies based on catalytic reagents.

机译：不对称共轭加成反应是有机铜化学中最流行的反应，可用于化学计量和催化生成立体异构中心。最近，基于催化试剂的策略已取得重要进展。

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《Angewandte Chemie》 |2004年第8期|共4页
作者
Susumu Saito; Hisashi Yamamoto; Hirotsugu Ito; Takashi Nagahara; Kazuaki Ishihara;
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正文语种 eng
中图分类应用化学;
关键词
aluminum; asymmetric synthesis; chiral auxiliaries; michael addition; molecular recognition;

机译：铝;不对称合成;手性助剂;迈克尔加成;分子识别;

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1. Chiral Molecular Recognition by Aluminum Tris (2,6-diphenylphenoxide) in an Asymmetric 1,4-Addition [J] . Susumu Saito, Hisashi Yamamoto, Hirotsugu Ito, Angewandte Chemie . 2004,第8期

机译：Tris（2,6-diphenylphenoxide）铝在不对称1,4-加成中的手性分子识别
2. Unprecedented Nucleophilic Addition of Organolithiums to Aromatic Aldehydes and Ketones by Complexation with Aluminum Tris(2,6-diphenylphenoxide) [J] . Keiji Maruoka, Masahiro Ito, Hisashi Yamamoto Journal of the American Chemical Society . 1995,第35期

机译：与铝三（2,6-二苯基苯氧基）络合使有机锂空前地亲核加成到芳香醛和酮上
3. Molecuar Recognition of Carbonyl Compounds Using Aluminum Tris(2,6-diphenylphenoxide) (ATPH):New Regio-and Stereoselective Alkylation of #alpha#,#beta#-Unsaturated Carbonyl Compounds [J] . Giovanni Casiraghi, Franca Zanardi, Giovanni Appendino Chemtracts . 2001,第2期

机译：三（2,6-二苯酚铝）（ATPH）铝对羰基化合物的分子识别：#alpha＃，＃beta＃-不饱和羰基化合物的新区域和立体选择性烷基化
4. Chiral Rhodium Nanoparticle-catalyzed Asymmetric 1,4- Addition Reactions of Arylboronic Acids with β,γ-Unsaturated α-Ketocarbonyl Compounds [C] . Zhiyuan ZHU, Hiroyuki MIYAMURA, Tomohiro YASUKAWA 日本化学会春季年会講演予稿集 . 2018

机译：手性铑纳米粒子催化的不对称1,4-添加芳基硼酸与β，γ-不饱和α-酮烷基化合物的反应
5. Advances in Hydroboration: Metal-Free Oxygen-Directed Hydroboration and Asymmetric Hydroboration with N-tosyl-(R,R)-2,6-diisopropyl-1,4,borazinane. [D] . Rarig, Robert-Andre F. 2010

机译：硼氢化研究的进展：无金属氧导向的硼氢化和与N-甲苯磺酰基-（R，R）-2,6-二异丙基-1,4，硼氮烷的不对称硼氢化。
6. Chirality recognition of winding vine-shaped heterobiaryls with molecular asymmetry. Kinetic and dynamic kinetic resolution by Shi’s asymmetric epoxidation [O] . Kazuki Maruhashi, Yoichi Okayama, Ryo Inoue, -1

机译：具有分子不对称性的缠绕藤状杂二芳基化合物的手性识别。 Shi的不对称环氧化反应的动力学和动态动力学拆分
7. Asymmetric 1,4-Additions to γ-Menthyloxybutenolides. Enantiospecific Synthesis of Chiral 1,4-Butanediols. [O] . Jansen Johan F.G.A., Feringa Bernard 1989

机译：γ-甲氧基丁烯内酯的不对称1,4-加成。手性1,4-丁二醇的对映体合成。
8. Addition Compounds of Alkali Metal Hydrides. 32. A Comparison Study of Chiral Trialkylborohydrides and Chiral Dialkylmonoalkoxyborohydrides for the Asymmetric Reduction of Prochiral Ketones: The Effect of Comparable Chiral Alkyl a [R] . Brown, H. C., Park, W. S., Cho, B. T. 1987

机译：碱金属氢化物的加成化合物。 32.手性三烷基硼氢化物和手性二烷基单烷氧基硼氢化物对前手性酮不对称还原的比较研究：可比较的手性烷基a的影响

Chiral Molecular Recognition by Aluminum Tris (2,6-diphenylphenoxide) in an Asymmetric 1,4-Addition

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