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'Chemical Bonding and Molecular Geometry': Comments on a Book Review

机译:“化学键和分子几何”:评论

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摘要

In a recent review of our book "Chemical Bonding and Molecular Geometry" Frenking praised certain features such as our treatment of the connection between dipole moments and the charge distribution of a molecule as well as the discussion of the Pauli principle as fundamental to the understanding of the electronic structure of molecules. However, he severely criticizes our use of the electron density rather than the wave function approach and our use of the VSEPR and LCP models as a basis for understanding chemical bonding. He cites many statements described as "absurdities" that we show are either incorrect quotations from the book, statement taken out of context, or statements that he has simply misunderstood.
机译:在最近对我们的《化学键合和分子几何学》一书的评论中,弗伦金赞扬了某些特征,例如我们对偶极矩与分子的电荷分布之间的联系的处理以及对保理原理的理解,这是理解分子的电子结构。但是,他严厉批评我们使用电子密度而不是波函数方法,以及使用VSEPR和LCP模型作为理解化学键的基础。他引用了许多我们称之为“荒谬”的陈述,这些陈述要么是书中的引文不正确,要么是脱离上下文的陈述,要么是他只是被误解了。

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