Radiolysis of Confined Water:Production and Reactivity of Hydroxyl Radicals

摘要

As technology progresses to the nanoscale,the question of how chemical reactions are perturbed by the size of the environment needs further consideration.Such supramolec-ular steric effects provide new strategies to orientate reactivity towards desired functionality.Confinement and interfacial phenomena are expected to have dramatic effects on reaction rates and mechanisms.